Cationic versus anionic Pt complex: The performance analysis of a hybrid-capacitor, DFT calculation and electrochemical properties

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dc.authoridDemirel, Serkan/0000-0003-1158-4956
dc.authoridYaşar, Sedat/0000-0001-7285-2761
dc.authoridAKKOÇ, Mitat/0000-0001-8641-8958
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridbruneau, christian/0000-0002-2220-1458
dc.authorwosidDemirel, Serkan/AAA-2133-2020
dc.authorwosidYaşar, Sedat/ABG-8356-2020
dc.authorwosidOz, Erdinc/GXW-0937-2022
dc.authorwosidAKKOÇ, Mitat/AAJ-5780-2020
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidbayri, ali/AAA-5966-2021
dc.authorwosidBruneau, Christian/AAL-4582-2020
dc.contributor.authorAkkoc, Mitat
dc.contributor.authorDemirel, Serkan
dc.contributor.authorOz, Erdinc
dc.contributor.authorAltin, Serdar
dc.contributor.authorBayri, Ali
dc.contributor.authorDorcet, Vincent
dc.contributor.authorRoisnel, Thierry
dc.date.accessioned2024-08-04T20:45:31Z
dc.date.available2024-08-04T20:45:31Z
dc.date.issued2019
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe synthesis and characterization of cationic versus anionic platinum(II) complex of the type [PtCl3(DMSO)](-)[NHC](+) (NHC: N-heterocyclic carbene) is reported for the first time. The complex 3 was synthesized from silver(I)-NHC2, and K-2[PtCl4] in DMSO at 80 degrees C under exclusion of light. The ionic platinum(II) complex was obtained in high yield and fully characterized by H-1, C-13, Pt-195 NMR and HRMS spectroscopy, X-ray diffraction and elemental analysis. The structural properties of the complex were investigated by using Gaussian suit and the obtained parameters were crosschecked with the X-ray data. The HOMO-LUMO energies and electrostatic surface mapping of the complex were calculated and the results were discussed with the capacitive properties of the complex. Electrochemical analysis by cyclic voltammetry (CV) of the complex shows reversible redox peaks about platinum center. The complex was used as an electrode material for the capacitor device and result is promising that the highest performance of complex 3 was found as 10.22 F/g. (C) 2018 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipInonu University/Turkey [G-2016/52]en_US
dc.description.sponsorshipDr. Serdar Akin want to thanks to Inonu University/Turkey for the financial support with project numbers of G-2016/52 for the measurement of the electrochemical and capacitive properties of complex.en_US
dc.identifier.doi10.1016/j.poly.2018.10.033
dc.identifier.endpage441en_US
dc.identifier.issn0277-5387
dc.identifier.issn1873-3719
dc.identifier.scopus2-s2.0-85055729470en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage434en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2018.10.033
dc.identifier.urihttps://hdl.handle.net/11616/98515
dc.identifier.volume157en_US
dc.identifier.wosWOS:000451791000053en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectPlatinum ionic complexen_US
dc.subjectRing-expanded N-heterocyclic carbeneen_US
dc.subjectHybrid capacitoren_US
dc.subjectDFTen_US
dc.subjectCyclic voltammetryen_US
dc.titleCationic versus anionic Pt complex: The performance analysis of a hybrid-capacitor, DFT calculation and electrochemical propertiesen_US
dc.typeArticleen_US

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