Palladium N-heterocyclic carbene complexes: Synthesis, characterization and catalytic properties in amination

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridDüşünceli, Serpil Demir/0000-0001-8765-4039
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authorwosidDemir, Serpil/AAI-1740-2019
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidSahin, Onur/KGM-3910-2024
dc.authorwosidDüşünceli, Serpil Demir/AAA-7160-2021
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorDemir, Serpil
dc.contributor.authorSahin, Onur
dc.contributor.authorBuyukgungor, Orhan
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2024-08-04T20:32:24Z
dc.date.available2024-08-04T20:32:24Z
dc.date.issued2010
dc.departmentİnönü Üniversitesien_US
dc.description.abstractTransmetalation has proved to be a promising procedure to obtain NHC-metal complexes, which typically involves treatment of the imidazolium salt with Ag2O to form the Ag-NHC complex, followed by transmetalation to a species such as [PdCl2(CH3CN)(2)] gave the palladium complex in which the N-heterocyclic carbene was bound to the metal center. New bis(NHC)-Pd complexes were synthesized and characterized by elemental analysis, H-1 NMR, C-13 NMR, and IR spectroscopy. The crystal and molecular structure of the trans-dichlorobis{1-(2,3,5,6-tetramethylbenzyl)-3-(2,3,4,5,6-pentamethylbenzyl)imidazolidin-2-yliden}palladium(II) complex was determined by single-crystal X-ray diffraction. The activity of the Pd(II) complexes in the coupling reaction of anilines or amines with bromobenzene was investigated. A preliminary catalytic study showed that these bis(NHC)-Pd complexes were highly active in the direct synthesis of triarylamines and secondary amines in a single step. (C) 2010 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUB_ITAK-CNRS (France) [TBAG-U/181 (106T716)]; Inonu University Research Fund [I.U. B.A.P: 2009/10]; University Research Fund [F279]en_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey TUB_ITAK-CNRS (France) [TBAG-U/181 (106T716)] and Inonu University Research Fund (I.U. B.A.P: 2009/10). The authors wish to acknowledge the Faculty of Arts and Sciences, Ondokuz Mayis University, Turkey, for the use of the Stoe IPDS-II diffractometer (purchased from grant no. F279 of the University Research Fund).en_US
dc.identifier.doi10.1016/j.jorganchem.2010.03.013
dc.identifier.endpage1560en_US
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.issue10-11en_US
dc.identifier.scopus2-s2.0-77953285807en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage1555en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2010.03.013
dc.identifier.urihttps://hdl.handle.net/11616/95054
dc.identifier.volume695en_US
dc.identifier.wosWOS:000277652500018en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectPalladium catalysisen_US
dc.subjectAminationen_US
dc.subjectTriarylaminesen_US
dc.subjectAminesen_US
dc.titlePalladium N-heterocyclic carbene complexes: Synthesis, characterization and catalytic properties in aminationen_US
dc.typeArticleen_US

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