A novel ditopic ring-expanded N-heterocyclic carbene ligand-assisted Suzuki-Miyaura coupling reaction in aqueous media

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dc.authoridYaşar, Sedat/0000-0001-7285-2761
dc.authoridkaraca, emine özge/0000-0003-2094-9742
dc.authoridTahir, Muhammad Nawaz/0000-0002-6815-9806
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridAKKOÇ, Mitat/0000-0001-8641-8958
dc.authorwosidYaşar, Sedat/ABG-8356-2020
dc.authorwosidkaraca, emine özge/AAH-2535-2019
dc.authorwosidTahir, Muhammad Nawaz/HPB-5726-2023
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidAKKOÇ, Mitat/AAJ-5780-2020
dc.contributor.authorKaraca, Emine Ozge
dc.contributor.authorAkkoc, Mitat
dc.contributor.authorTahir, Muhammad Nawaz
dc.contributor.authorArici, Cengiz
dc.contributor.authorImik, Fatma
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorYasar, Sedat
dc.date.accessioned2024-08-04T20:43:56Z
dc.date.available2024-08-04T20:43:56Z
dc.date.issued2017
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA series of seven-membered ditopic ring-expanded N-heterocyclic carbene (dre-NHC) precursors, bearing sterically demanding and electron-rich aryl groups, were synthesised in moderate yields via the reaction of 1,2,4,5-tetrakis(bromomethyl)benzene with the corresponding N,N'-diarylformamidines in the presence of K2CO3 in acetonitrile under an air atmosphere. All new compounds were characterised by HRMS, NMR spectroscopy, and microanalysis, as well as X-ray crystallography for compound lc. The development of an efficient catalytic system for the Suzuki-Miyaura coupling reaction of aryl chlorides with various boronic acids was also investigated using the in situ generated dre-NHC ligands. (C) 2017 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK Project) [113Z285]en_US
dc.description.sponsorshipThis work was financially supported by The Scientific and Technological Research Council of Turkey (TUBITAK Project No.: 113Z285).en_US
dc.identifier.doi10.1016/j.tetlet.2017.07.096
dc.identifier.endpage3532en_US
dc.identifier.issn0040-4039
dc.identifier.issue36en_US
dc.identifier.scopus2-s2.0-85026795462en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage3529en_US
dc.identifier.urihttps://doi.org/10.1016/j.tetlet.2017.07.096
dc.identifier.urihttps://hdl.handle.net/11616/97917
dc.identifier.volume58en_US
dc.identifier.wosWOS:000409153900011en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofTetrahedron Lettersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectDitopic ring-expanded N-heterocyclic carbeneen_US
dc.subjectSuzuki-Miyaura couplingen_US
dc.subjectC-C bond formationen_US
dc.subjectPalladiumen_US
dc.titleA novel ditopic ring-expanded N-heterocyclic carbene ligand-assisted Suzuki-Miyaura coupling reaction in aqueous mediaen_US
dc.typeArticleen_US

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