The first neutral, mononuclear 4f metal thiolates and new methods for corresponding aryl oxides and bis(trimethylsilyl)amides

dc.authorscopusid7006471258
dc.authorscopusid36038085300
dc.authorscopusid35446756800
dc.authorscopusid55727385300
dc.contributor.authorCetinkaya B.
dc.contributor.authorHitchcock P.B.
dc.contributor.authorLappert M.F.
dc.contributor.authorSmith R.G.
dc.date.accessioned2024-08-04T19:59:09Z
dc.date.available2024-08-04T19:59:09Z
dc.date.issued1992
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe first neutral, mononuclear 4f thiolates, [Sm(SAr)3] 1 and [Yb(SAr)2(dme)2] 2, have been prepared, and X-ray characterised [<Sm-S> 2.645(9) Å, <Yb-S> 2.756(8) Å], 1 from [Sm(CHR?2)3] + 3ArSH and 2 from [Yb(NR?2)2(dme)2] [obtained from Yb + Sn(NR?2)2]; 1 was not readily accessible from ArSH and Yb in liquid NH3, although replacing ArSH by Ar?OH yielded [Yb(OAr?)2(thf)3] [Ar = C6H 2But3-2,4,6; Ar? = C6H 2But2-2,6-Me-4; R? = SiMe 3? dme = (MeOCH2)2, thf = OC 4H8].en_US
dc.identifier.doi10.1039/C39920000932
dc.identifier.endpage934en_US
dc.identifier.issn0022-4936
dc.identifier.issue13en_US
dc.identifier.scopus2-s2.0-37049078301en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage932en_US
dc.identifier.urihttps://doi.org/10.1039/C39920000932
dc.identifier.urihttps://hdl.handle.net/11616/90428
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.relation.ispartofJournal of the Chemical Society, Chemical Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject[No Keyword]en_US
dc.titleThe first neutral, mononuclear 4f metal thiolates and new methods for corresponding aryl oxides and bis(trimethylsilyl)amidesen_US
dc.typeArticleen_US

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