Preparation of Mixed Bis-N-Heterocyclic Carbene Rhodium(I) Complexes

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dc.authoridPerez-Torrente, Jesus J./0000-0002-3327-0918
dc.authoridPassarelli, Vincenzo/0000-0002-1735-6439
dc.authoridAZPIROZ, RAMON/0000-0002-0096-1560
dc.authoridOzdemir, Ismail/0000-0001-6325-0216
dc.authorwosidCastarlenas, Ricardo/E-3641-2016
dc.authorwosidPerez-Torrente, Jesus J./F-3569-2011
dc.contributor.authorAzpiroz, Ramon
dc.contributor.authorOlgun Karatas, Mert
dc.contributor.authorPassarelli, Vincenzo
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorPerez-Torrente, Jesus J.
dc.contributor.authorCastarlenas, Ricardo
dc.date.accessioned2024-08-04T20:53:05Z
dc.date.available2024-08-04T20:53:05Z
dc.date.issued2022
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA series of mixed bis-NHC rhodium(I) complexes of type RhCl(eta(2)-olefin)(NHC)(NHC') have been synthesized by a stepwise reaction of [Rh(mu-Cl)(eta(2)-olefin)(2)](2) with two different NHCs (NHC = N-heterocyclic carbene), in which the steric hindrance of both NHC ligands and the eta(2)-olefin is critical. Similarly, new mixed coumarin-functionalized bis-NHC rhodium complexes have been prepared by a reaction of mono NHC complexes of type RhCl(NHC-coumarin)(eta(2),eta(2)-cod) with the corresponding azolium salt in the presence of an external base. Both synthetic procedures proceed selectively and allow the preparation of mixed bis-NHC rhodium complexes in good yields.en_US
dc.description.sponsorshipSpanish Ministerio de Ciencia e Innovacion [MCIN/AEI/10.13039/501100011033, PID2019-103965GB-I00]; Departamento de Ciencia, Universidad y Sociedad del Conocimiento del Gobierno de Aragon [E42_20R]en_US
dc.description.sponsorshipFinancial support from the Spanish Ministerio de Ciencia e Innovacion MCIN/AEI/10.13039/501100011033, under the Project PID2019-103965GB-I00, and the Departamento de Ciencia, Universidad y Sociedad del Conocimiento del Gobierno de Aragon (group E42_20R).en_US
dc.identifier.doi10.3390/molecules27207002
dc.identifier.issn1420-3049
dc.identifier.issue20en_US
dc.identifier.pmid36296594en_US
dc.identifier.scopus2-s2.0-85140864596en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.3390/molecules27207002
dc.identifier.urihttps://hdl.handle.net/11616/100965
dc.identifier.volume27en_US
dc.identifier.wosWOS:000875074700001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherMdpien_US
dc.relation.ispartofMoleculesen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectcoumarinen_US
dc.subjectrhodiumen_US
dc.subjectmixed-NHCen_US
dc.subjectanagostic interactionsen_US
dc.titlePreparation of Mixed Bis-N-Heterocyclic Carbene Rhodium(I) Complexesen_US
dc.typeArticleen_US

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