Direct arylation of arene C-H bonds by cooperative action of NHCarbene-Ruthenium(II) catalyst and carbonate via proton abstraction mechanism

Basit Öğe Kaydı
dc.authoridMaseras, Feliu/0000-0001-8806-2019
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridDüşünceli, Serpil Demir/0000-0001-8765-4039
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authoridbruneau, christian/0000-0002-2220-1458
dc.authorwosidMaseras, Feliu/B-1002-2008
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidDemir, Serpil/AAI-1740-2019
dc.authorwosidBruneau, Christian/AAL-4582-2020
dc.authorwosidDüşünceli, Serpil Demir/AAA-7160-2021
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorDemir, Serpil
dc.contributor.authorCetinkaya, Bekir
dc.contributor.authorGourlaouen, Christophe
dc.contributor.authorMaseras, Feliu
dc.contributor.authorBruneau, Christian
dc.contributor.authorDixneuf, Pierre H.
dc.date.accessioned2024-08-04T20:30:40Z
dc.date.available2024-08-04T20:30:40Z
dc.date.issued2008
dc.departmentİnönü Üniversitesien_US
dc.description.abstractDirect functionalization of sp(2) C-H bonds via ortho diarylation of 2-pyridyl benzene with arylbromides was achieved using ruthenium(II) catalysts containing a RuCl2(NHC) unit and generated from [RuCl2(arene)](2) and two types of NHC precursors, pyrimidinium and benzimidazolium salts, in the presence of Cs2CO3. DFT calculations from RuCl2(NHC)(2-pyridylbenzene) show that a proton abstraction mechanism, on cooperative actions of both the coordinated base and the Ru(II) center, is favoured via a 13.7 kcal mol(-1) exothermic process affording an orthometalated intermediate with a 2.009 angstrom Ru-C bond.en_US
dc.identifier.doi10.1021/ja710276x
dc.identifier.endpage+en_US
dc.identifier.issn0002-7863
dc.identifier.issue4en_US
dc.identifier.pmid18183987en_US
dc.identifier.scopus2-s2.0-38649141502en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage1156en_US
dc.identifier.urihttps://doi.org/10.1021/ja710276x
dc.identifier.urihttps://hdl.handle.net/11616/94443
dc.identifier.volume130en_US
dc.identifier.wosWOS:000252634600022en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofJournal of The American Chemical Societyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAryl Chloridesen_US
dc.subjectIntramolecular Arylationen_US
dc.subjectRuthenium Complexesen_US
dc.subjectMultiple Arylationen_US
dc.subjectCoupling Reactionsen_US
dc.subjectPhosphine Oxidesen_US
dc.subjectOrganic Halidesen_US
dc.subjectActivationen_US
dc.subjectDerivativesen_US
dc.subjectBromidesen_US
dc.titleDirect arylation of arene C-H bonds by cooperative action of NHCarbene-Ruthenium(II) catalyst and carbonate via proton abstraction mechanismen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
PubMed İndeksli Yayın Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu