Metal-Free a Simple and Versatile N ? B Dative Bond Stabilized Boron-Based Catalysts for Transfer Hydrogenation of Aromatic Ketones

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dc.authoridKilic, Ahmet/0000-0001-9073-4339
dc.authoridSoylemez, Rahime/0000-0003-3287-9243
dc.authorwosidSöylemez, Rahime Yavuz/JGE-4956-2023
dc.authorwosidKilic, Ahmet/B-8904-2012
dc.authorwosidYavuz, Rahime/JGE-2713-2023
dc.contributor.authorSoylemez, Rahime
dc.contributor.authorKilic, Ahmet
dc.contributor.authorKaraca, Emine Ozge
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:53:31Z
dc.date.available2024-08-04T20:53:31Z
dc.date.issued2024
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this study, novel boron-containing salen ligands (1 and 2) and their tetra-coordinated boron-based polymers (1a-b and 2a-b) containing N -> B coordination bonds were synthesized under suitable conditions. In the first step, the synthesis of boron-containing salen ligands (1 and 2) was carried out as a result of the reaction of 4-formyl phenylboronic acid with different primary amines. Then, the obtained boron-containing salen ligands (1 and 2) were reacted with pentaerythritol and different N-donor ligands, respectively, to synthesize tetra-coordinated polymers (1a-b and 2a-b) containing N -> B coordination bonds. Synthesized boron-containing salen ligands and corresponding tetra-coordinated polymers containing (N -> B) coordination bonds were characterized by melting point, elemental analysis, LC-MS/MS spectrometer, FT-IR, UV-Vis and NMR (H-1, C-13, and B-11) spectroscopy for illuminate of their structures. The use of synthesized boron-containing salen ligands (1 and 2) and their polymers (1a-b and 2a-b) containing N -> B coordination bonds as novel organocatalysts were tested for the transfer hydrogenation of various aromatic ketones under suitable conditions. Considering all the catalytic results, it was seen that salen ligands (1 and 2) and tetra-coordinated boron-based polymers (1a-b and 2a-b) containing N -> B coordination bonds to be suitable organocatalysts in the future for transfer hydrogenation with other boron compounds. [GRAPHICS]en_US
dc.description.sponsorshipHarran Universityen_US
dc.description.sponsorshipThis study was supported by the Harran University Research Fund.en_US
dc.identifier.doi10.1007/s10562-023-04312-3
dc.identifier.endpage327en_US
dc.identifier.issn1011-372X
dc.identifier.issn1572-879X
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-85149461671en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage314en_US
dc.identifier.urihttps://doi.org/10.1007/s10562-023-04312-3
dc.identifier.urihttps://hdl.handle.net/11616/101206
dc.identifier.volume154en_US
dc.identifier.wosWOS:000954425100001en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofCatalysis Lettersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBoron-based polymersen_US
dc.subjectBoronic acidsen_US
dc.subjectSpectroscopy propertiesen_US
dc.subjectTransfer hydrogenationen_US
dc.titleMetal-Free a Simple and Versatile N ? B Dative Bond Stabilized Boron-Based Catalysts for Transfer Hydrogenation of Aromatic Ketonesen_US
dc.typeArticleen_US

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