2-Hydroxyethyl-Substituted (NHC)Pd(II)PPh3 Complexes: Synthesis, Characterization, Crystal Structure and Its Application on Sonogashira Cross-Coupling Reactions in Aqueous Media

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dc.authoridAygün, Muhittin/0000-0001-9670-9062
dc.authoridAktaş, Aydın/0000-0001-8496-6782;
dc.authorwosidAygün, Muhittin/P-3605-2019
dc.authorwosidAktaş, Aydın/J-6194-2019
dc.authorwosidBarut Celepci, Duygu/M-6189-2017
dc.authorwosidGök, Yetkin/AAA-5669-2021
dc.contributor.authorAktas, Aydin
dc.contributor.authorCelepci, Duygu Barut
dc.contributor.authorGok, Yetkin
dc.contributor.authorAygun, Muhittin
dc.date.accessioned2024-08-04T20:45:30Z
dc.date.available2024-08-04T20:45:30Z
dc.date.issued2018
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThis study contains the synthesis of the novel series of the 2- hydroxyethyl substituted Pd-based N-heterocyclic carbene (NHC) / triphenylphosphine (PPh3) complexes. The (NHC)Pd(II)PPh3 complexes have been prepared from the PPh3 ligand, replaced by 3-chloro pyridine ligand in (NHC)Pd(II)(3-Cl-pyridine) complexes. The novel 2-hydroxyethyl substituted (NHC)Pd(II)PPh3 complexes have been characterized by using (HNMR)-H-1, C-13 {H-1}NMR, P-31 {H-1}NMR, FTIR spectroscopy, and elemental analysis techniques. Molecular and crystal structure of 1f was obtained by using single-crystal X-ray diffraction method. The novel 2-hydroxyethyl substituted (NHC)Pd(II)PPh3 complexes have been examined as catalysts in the Sonogashira cross-coupling reactions aqueous medium and demonstrated excellent activity in this reaction.en_US
dc.description.sponsorshipDokuz Eylul University for the use of the Rigaku Oxford Xcalibur Eos Diffractometer (purchased under University) [2010.KB.FEN.13]en_US
dc.description.sponsorshipThe authors acknowledge Dokuz Eylul University for the use of the Rigaku Oxford Xcalibur Eos Diffractometer (purchased under University Research Grant No: 2010.KB.FEN.13). The authors thank the Inonu University Faculty of Science Department of Chemistry for the spectroscopy and elemental analysis characterization of compounds.en_US
dc.identifier.doi10.1002/slct.201802519
dc.identifier.endpage10937en_US
dc.identifier.issn2365-6549
dc.identifier.issue39en_US
dc.identifier.scopus2-s2.0-85055268076en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage10932en_US
dc.identifier.urihttps://doi.org/10.1002/slct.201802519
dc.identifier.urihttps://hdl.handle.net/11616/98504
dc.identifier.volume3en_US
dc.identifier.wosWOS:000449032600017en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofChemistryselecten_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCrystal structureen_US
dc.subjectN-Heterocyclic carbenesen_US
dc.subjectPalladium complexen_US
dc.subjectSonogashira reactionsen_US
dc.subjectTriphenylphosphineen_US
dc.title2-Hydroxyethyl-Substituted (NHC)Pd(II)PPh3 Complexes: Synthesis, Characterization, Crystal Structure and Its Application on Sonogashira Cross-Coupling Reactions in Aqueous Mediaen_US
dc.typeArticleen_US

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