Synthesis and radical polymerization of 2-(vinylbenzylmercapto) heterocyclic salts
Küçük Resim Yok
Tarih
1999
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Vsp Bv
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Heterocyclic group-containing vinyl monomers, 2-(vinylbenzylmercapto) heterocyclic salts, were synthesized and their polymerization and copolymerization with styrene were investigated. Cyclic thioureas incorporating imidazoline, hexahydropyrimidine and benzimidazole nuclei were alkylated by chloromethyl styrene to give quaternary salts that were used as monomers. Homopolymerization of the monomers afforded mainly soluble polymers on high dilution. In the copolymerization with styrene, an alternating nature was suggested from the copolymerization parameters obtained by either the Finemann-Ross method or the Mao-Huglin method. A decrease in alternating copolymerizability was demonstrated.
Açıklama
Anahtar Kelimeler
2-vinylbenzylmercapto, heterocyclic salts, radical polymerization, reactivity parameters, imidazoline
Kaynak
Designed Monomers and Polymers
WoS Q Değeri
N/A
Scopus Q Değeri
N/A
Cilt
2
Sayı
3
