INTERFERENCES IN THE DETERMINATION OF LITHIUM BY FLAME ATOMIC-EMISSION SPECTROMETRY WITH PLATINUM-LOOP ATOMIZER

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dc.authoridÖzdemir, Yüksel/0000-0001-7089-3690
dc.authorwosidÖzdemir, Yüksel/F-7652-2016
dc.contributor.authorOZDEMIR, Y
dc.contributor.authorKARAGOZLER, AE
dc.contributor.authorGUCER, S
dc.date.accessioned2024-08-04T20:11:45Z
dc.date.available2024-08-04T20:11:45Z
dc.date.issued1994
dc.departmentİnönü Üniversitesien_US
dc.description.abstractAlthough flame atomic emission spectrometry (AES) is the most popular method for the determination of Li, the method is subject to interference from alkaline and alkaline earth elements. The effects of CaOH and SrO emission bands are particularly severe. The use of a Pt-loop atomizer was found to eliminate interference from Ca and Sr, as salts of these elements remained as solid residues on the loop material. High contents of F-, Cl-, SO42- and PO43- were found to reduce the U signal, this was largely due to loss of LiCl in the case of Cl-, in the case of F-, SO42- and PO43-, the reduction in the Li signal was due to lithium oxide formation. The accuracy of the Pt-loop technique was shown to be satisfactory in matrices of high Ca and Sr contents. The detection limit obtained with the Pt-loop was at least one order of magnitude better than that of conventional AES. The technique was applied in the determination of Li in several sample types.en_US
dc.identifier.doi10.1039/ja9940900797
dc.identifier.endpage800en_US
dc.identifier.issn0267-9477
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-0000849116en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage797en_US
dc.identifier.urihttps://doi.org/10.1039/ja9940900797
dc.identifier.urihttps://hdl.handle.net/11616/92973
dc.identifier.volume9en_US
dc.identifier.wosWOS:A1994NZ58100010en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherRoyal Soc Chemistryen_US
dc.relation.ispartofJournal of Analytical Atomic Spectrometryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectINTERFERENCESen_US
dc.subjectLITHIUM DETERMINATIONen_US
dc.subjectFLAME ATOMIC EMISSION SPECTROMETRYen_US
dc.subjectPLATINUM-LOOP ATOMIZERen_US
dc.titleINTERFERENCES IN THE DETERMINATION OF LITHIUM BY FLAME ATOMIC-EMISSION SPECTROMETRY WITH PLATINUM-LOOP ATOMIZERen_US
dc.typeArticleen_US

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