Structure, CO-releasing property, electrochemistry, DFT calculation, and antioxidant activity of benzimidazole derivative substituted [Mn(CO)3(bpy)L]PF6 type novel manganese complexes

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dc.authoridÇelebi, Mutlu Sönmez/0000-0002-8816-6763
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridDüşünceli, Serpil Demir/0000-0001-8765-4039
dc.authoridÜstün, Elvan/0000-0002-0587-7261
dc.authorwosidÇelebi, Mutlu Sönmez/X-1055-2019
dc.authorwosidDemir, Serpil/AAI-1740-2019
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidDüşünceli, Serpil Demir/AAA-7160-2021
dc.authorwosidÜstün, Elvan/HJB-1157-2022
dc.contributor.authorUstun, Elvan
dc.contributor.authorAyvaz, Melek Col
dc.contributor.authorCelebi, Mutlu Sonmez
dc.contributor.authorAsci, Gizem
dc.contributor.authorDemir, Serpil
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:41:48Z
dc.date.available2024-08-04T20:41:48Z
dc.date.issued2016
dc.departmentİnönü Üniversitesien_US
dc.description.abstractMetal carbonyl complexes are prominent group organometallic compounds because of their applications in industrial and pharmaceutical chemistry. In recent years, metal carbonyl complexes have been accepted major for storage and transportation of carbon monoxide which is an important signaling molecule significantly in pathogenesis of some diseases. Thus, we designed and synthesized novel manganese (I) carbonyl complexes with general formula [Mn(CO)(3)(bpy)L]PF6 (bpy = 2,2-bipyridyl, L = N-(2-chlorobenzyl) benzimidazole, N-(2-methoxybenzyl) benzimidazole, N-(2-methylbenzyl) benzimidazole). The complex molecules were characterized by LC-MS, H-1-NMR, C-13-NMR, IR spectroscopy methods and elemental analysis. The CO-releasing properties, antioxidant activities and redox properties of these complexes were investigated. The DFT/TDDFT analyses were made by ORCA package program. (C) 2016 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipScientific and Technological Research Council of Turkey (TUBITAK) [112T320]en_US
dc.description.sponsorshipSupport of Scientific and Technological Research Council of Turkey (TUBITAK, Project No: 112T320) is gratefully acknowledged.en_US
dc.identifier.doi10.1016/j.ica.2016.05.027
dc.identifier.endpage189en_US
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopus2-s2.0-84973165255en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage182en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2016.05.027
dc.identifier.urihttps://hdl.handle.net/11616/97356
dc.identifier.volume450en_US
dc.identifier.wosWOS:000381964100024en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCORMsen_US
dc.subjectManganese complexesen_US
dc.subjectAntioxidanten_US
dc.subjectElectrochemistryen_US
dc.subjectDFT/TDDFTen_US
dc.titleStructure, CO-releasing property, electrochemistry, DFT calculation, and antioxidant activity of benzimidazole derivative substituted [Mn(CO)3(bpy)L]PF6 type novel manganese complexesen_US
dc.typeArticleen_US

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