N-alkylbenzimidazolepalladium(II) complexes: Synthesis and their catalytic activities in direct C-H functionalization of pyrrole, furan and 2-acetylthiophene

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dc.authoridÖzdemir, Namık/0000-0003-3371-9874
dc.authorwosidÖzdemir, Namık/J-6434-2015
dc.contributor.authorCicek, Metin
dc.contributor.authorIspir, Esin
dc.contributor.authorOzdemir, Namik
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:56:09Z
dc.date.available2024-08-04T20:56:09Z
dc.date.issued2024
dc.departmentİnönü Üniversitesien_US
dc.description.abstractHerein, we reported the synthesis of six new palladium complexes ( 2a-2f ) containing benzimidazole core and examined their catalytic activities in the direct arylation of heteroaromatic species with aryl bromides. For this purpose, a new series of palladium(II) complexes bearing N-coordinated benzimidazole complexes have been synthesized and fully characterized by elemental analysis, FT-IR, 1 H NMR and 13 C NMR spectroscopies. Additionally, the structures of the complexes 2a- 2e have been characterized by X-ray crystallography. Further, direct arylation reactions, using KOAc as base and DMAc as solvent under inert conditions, were carried out with the synthesized complexes in the presence of various aryl bromides, and 1-methylpyrrole-2-carboxaldehyde, furfuryl acetate, 2-acetylfuran and 2-acetylthiophene. Moreover, moderate to high yields were obtained in the direct arylation of heteroarenes and aryl bromides under 1 % mol catalyst loading conditions.en_US
dc.description.sponsorshipScientific Research Projects Unit of Inonue University [FBG-2021-2562]en_US
dc.description.sponsorshipThis study was supported by the Scientific Research Projects Unit of Inonue University (Project no.: FBG-2021-2562) .en_US
dc.identifier.doi10.1016/j.jorganchem.2024.123231
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.scopus2-s2.0-85197350313en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2024.123231
dc.identifier.urihttps://hdl.handle.net/11616/102090
dc.identifier.volume1016en_US
dc.identifier.wosWOS:001264932700001en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-alkylbenzimidazol palladium(II) complexesen_US
dc.subjectC-H bond activationen_US
dc.subjectC-H bond functionalization of heteroaromaticen_US
dc.subjectcompoundsen_US
dc.titleN-alkylbenzimidazolepalladium(II) complexes: Synthesis and their catalytic activities in direct C-H functionalization of pyrrole, furan and 2-acetylthiopheneen_US
dc.typeArticleen_US

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