Crystal structure of [RuCl2[N-(2,4,6-trimethyl-benzyl)N-(n-butyl)]-imidazolidin-2-ylidene] and [RuCl2[N-(2,4,6-trimethyl-benzyl)-N-(2-methoxyethyl)]imidazolidin-2-ylidene]

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dc.authoridArslan, Hakan/0000-0003-0046-9442
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridDüşünceli, Serpil Demir/0000-0001-8765-4039
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authorwosidDemir, Serpil/AAI-1740-2019
dc.authorwosidArslan, Hakan/B-1081-2008
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidDüşünceli, Serpil Demir/AAA-7160-2021
dc.contributor.authorArslan, H
dc.contributor.authorVanDerveer, D
dc.contributor.authorOzdemir, I
dc.contributor.authorCetinkaya, B
dc.contributor.authorDemir, S
dc.date.accessioned2024-08-04T20:14:49Z
dc.date.available2024-08-04T20:14:49Z
dc.date.issued2005
dc.departmentİnönü Üniversitesien_US
dc.description.abstractTwo imidazolidin ruthenium complexes, [RuCl2[N-(2,4,6-trimethyl-benzyl)-N-(n-butyl)]imidazolidin-2-ylidene], 1, and [RuCl2[N-(2,4,6-trimethyl-benzyl)-N-(2-methoxyethyl)]imidazolidin-2-ylidene], 2, have been synthesised and their crystal structures have been determined from single crystal X-ray diffraction data. Compound I is monoclinic, of space group C2/c with a = 18.466(4) angstrom, b = 14.816(3) angstrom, c = 15.413(3) angstrom, beta = 118.067(2)degrees, and V = 3720.9(12) angstrom(3) with Z = 8 for d(calc) = 1.536 g/cm(3). Compound 2 is monoclinic, of space group P2(1)/c with a = 8.1800(5) angstrom, b = 14.344(8) angstrom, c = 14.809(9), beta = 91.604(10)degrees, and V = 1736.7(18) angstrom(3) with Z = 4 for d(calc) = 1.653 g/cm(3). In each complex the ligand functions as an arene and carbene, occupying four coordination sites. The two chlorines in each compound complete a distorted octahedron.en_US
dc.identifier.doi10.1007/s10870-005-2442-y
dc.identifier.endpage495en_US
dc.identifier.issn1074-1542
dc.identifier.issue6en_US
dc.identifier.scopus2-s2.0-21644463482en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage491en_US
dc.identifier.urihttps://doi.org/10.1007/s10870-005-2442-y
dc.identifier.urihttps://hdl.handle.net/11616/93991
dc.identifier.volume35en_US
dc.identifier.wosWOS:000229747800011en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringer/Plenum Publishersen_US
dc.relation.ispartofJournal of Chemical Crystallographyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectcarbenesen_US
dc.subjectarenesen_US
dc.subjectruthenium complexesen_US
dc.subjectX-ray structuresen_US
dc.titleCrystal structure of [RuCl2[N-(2,4,6-trimethyl-benzyl)N-(n-butyl)]-imidazolidin-2-ylidene] and [RuCl2[N-(2,4,6-trimethyl-benzyl)-N-(2-methoxyethyl)]imidazolidin-2-ylidene]en_US
dc.typeArticleen_US

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