Synthesis and characterization of N-substituted 1,4,5,6-tetrahydropyrimidine containing functional polymers as SO2 and CO2 sorbents

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dc.authoridSEÇKİN, Turgay/0000-0001-8483-7366
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authorwosidSEÇKİN, Turgay/ABG-7537-2020
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorSeckin, T
dc.contributor.authorAlici, B
dc.contributor.authorCetinkaya, E
dc.contributor.authorOzdemir, I
dc.date.accessioned2024-08-04T20:11:54Z
dc.date.available2024-08-04T20:11:54Z
dc.date.issued1997
dc.departmentİnönü Üniversitesien_US
dc.description.abstractNovel vinyl monomers containing 1,4,5,6-tetrahydropyrimidine were prepared by the reaction of N-substituted-1,3-diaminopropane with N,N-dimethyl-formamide dimethylacetal, which gave l-alkyl or aryl substituted 1,4,5,6-tetrahydropyrimidines, Alkylation of the tetrahydropyrimidine derivatives by chloromethylstyrene produces the N-methyl-N'-vinyl benzyl-1,4,5,6-tetrahydropyrimidinium chloride in high yields, These monomers were readily polymerized in dimethylformamide by AIBN at 80 degrees C. Homopolymers and soluble linear copolymers were prepared and copolymerization parameters were rationalized. Further, insoluble terpolymers prepared from these monomers, styrene and divinylbenzene were tested for the sorption of the weakly acidic gases gave excellent results. (C) 1997 John Wiley & Sons, Inc.en_US
dc.identifier.doi10.1002/(SICI)1099-0518(19970915)35:12<2411
dc.identifier.endpage2420en_US
dc.identifier.issn0887-624X
dc.identifier.issue12en_US
dc.identifier.scopus2-s2.0-0031220214en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage2411en_US
dc.identifier.urihttps://doi.org/10.1002/(SICI)1099-0518(19970915)35:12<2411
dc.identifier.urihttps://hdl.handle.net/11616/93080
dc.identifier.volume35en_US
dc.identifier.wosWOS:A1997XN89600011en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherJohn Wiley & Sons Incen_US
dc.relation.ispartofJournal of Polymer Science Part A-Polymer Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectfunctional polymersen_US
dc.subjectSO2 sorbentsen_US
dc.subject1,4,5,6-tetrahydropyrimidineen_US
dc.subjectcopolymerization parametersen_US
dc.subjectN-substituted tetrahydropyrimidineen_US
dc.titleSynthesis and characterization of N-substituted 1,4,5,6-tetrahydropyrimidine containing functional polymers as SO2 and CO2 sorbentsen_US
dc.typeArticleen_US

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