Phosphorus-nitrogen compounds

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dc.authoridBegeç, Saliha/0000-0001-5331-6736
dc.authoridHokelek, Tuncer/0000-0002-8602-4382;
dc.authorwosidBegeç, Saliha/AAA-9708-2021
dc.authorwosidHokelek, Tuncer/G-6068-2013
dc.authorwosidHokelek, Tuncer/JCE-0691-2023
dc.contributor.authorKiliç, A
dc.contributor.authorBegeç, S
dc.contributor.authorKiliç, Z
dc.contributor.authorHökelek, T
dc.date.accessioned2024-08-04T20:12:11Z
dc.date.available2024-08-04T20:12:11Z
dc.date.issued2000
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe reactions of Cl3P=N-P(O)Cl-2 (1) with Sodium 2,4,6-tert-butylphenoxide and sodium 2,6-di-tert-butyl-4-methylphenoxide give geminal bis products (2) and (3), respectively. Compounds (2) and (3) have been characterised by elemental analysis, IR, H-1-, C-13 and P-31-NMR and the structure of compound (2) has been examined crystallographically. It crystallizes in the monoclinic space group P2(1)/n with a = 10.056(1), b = 25.986(1), c = 15.533(1)Angstrom, beta = 95.9(1)degrees, V = 4037.6(1)Angstrom(3), Z = 4 and D-x = 1.19 g cm(-3). The bulky substituents are instrumental in determining the molecular geometry. The P-N bonds have neither single-nor double-bond character and are substantially shorter than the ideal P-N single bond. The P=O double bond is abnormally long and it has a single bond character. The P-N-P angle [158.0(3)degrees] is the largest one for the reported acyclic phosphazene derivatives in the literature. (C) 2000 Elsevier Science B.V. All rights reserved.en_US
dc.identifier.doi10.1016/S0022-2860(99)00232-X
dc.identifier.endpage262en_US
dc.identifier.issn0022-2860
dc.identifier.issue2-3en_US
dc.identifier.scopus2-s2.0-0034711781en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage255en_US
dc.identifier.urihttps://doi.org/10.1016/S0022-2860(99)00232-X
dc.identifier.urihttps://hdl.handle.net/11616/93278
dc.identifier.volume516en_US
dc.identifier.wosWOS:000084761200016en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Bven_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectphosphorus-nitrogen compoundsen_US
dc.subjectcrystal structures of phosphazene compoundsen_US
dc.subjectspectroscopic studies of phosphazene derivativesen_US
dc.subjectphenolysis of acyclic monophosphazeneen_US
dc.titlePhosphorus-nitrogen compoundsen_US
dc.typeArticleen_US

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