Ruthenium(II)-(p-cymene)-N-Heterocyclic Carbene Complexes for the N-Alkylation of Amine Using the Green Hydrogen Borrowing Methodology

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dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridKaloğlu, Murat/0000-0002-2770-5532
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidKaloğlu, Murat/AAA-3956-2021
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorKaloglu, Murat
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorSemeril, David
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:44:24Z
dc.date.available2024-08-04T20:44:24Z
dc.date.issued2018
dc.departmentİnönü Üniversitesien_US
dc.description.abstractSix ruthenium(II) complexes with the general molecular formula [RuCl2(NHC)((6)-p-cymene)] (NHC = N-heterocyclic carbene) were synthesized by the transmetalation method from [RuCl2((6)-p-cymene)](2) and silver(I)-NHC complexes. All complexes were fully characterized by analytical and spectral methods (FT-IR, elemental analysis and H-1 and C-13 NMR). The solid-state structure of one of the ruthenium complexes [dichloro-{1-[2-(2-ethoxyphenoxy)ethyl]-3-(3,5-dimethylbenzyl)benzimidazol-2-ylidene}(p-cymene) ruthenium(II)] has been established by single-crystal X-ray diffraction study, which revealed that the ruthenium atom adopt a classical piano-stool coordination geometry. Under the optimised conditions, these ruthenium complexes were found to be efficient catalysts for N-alkylation of aniline with arylmethyl alcohols using the hydrogen borrowing strategy, which is a cost-effective and environmentally attractive reaction for the preparation of N-alkylated amines.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK [112T303]en_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey TUBITAK (112T303).en_US
dc.identifier.doi10.1002/ejic.201701479
dc.identifier.endpage1243en_US
dc.identifier.issn1434-1948
dc.identifier.issn1099-0682
dc.identifier.issue10en_US
dc.identifier.scopus2-s2.0-85043992469en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1236en_US
dc.identifier.urihttps://doi.org/10.1002/ejic.201701479
dc.identifier.urihttps://hdl.handle.net/11616/98198
dc.identifier.wosWOS:000427471900011en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofEuropean Journal of Inorganic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectN-Heterocyclic carbenesen_US
dc.subjectRutheniumen_US
dc.subjectAminesen_US
dc.subjectN-Alkylationen_US
dc.subjectHydrogen borrowing strategyen_US
dc.titleRuthenium(II)-(p-cymene)-N-Heterocyclic Carbene Complexes for the N-Alkylation of Amine Using the Green Hydrogen Borrowing Methodologyen_US
dc.typeArticleen_US

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