In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[RuCl_2(p-cymene)]_2 system for transfer hydrogenation reactions

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Küçük Resim

Tarih

2011

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Turkish Journal of Chemistry

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

Abstract: Hydrogen-transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity. In the present study novel ruthenium carbene complexes were generated in situ and tested for their transfer hydrogenation reactions. The in situ prepared 3 component 1,3- dialkyltetrahydropyrimidinium salts (LHX)/[RuCl2(p?cymene)]2 and KOH catalyzed quantitatively the transfer hydrogenation of ketones under mild reaction conditions in 2-propanol.

Açıklama

Anahtar Kelimeler

Kaynak

Turkish Journal of Chemistry

WoS Q Değeri

Scopus Q Değeri

Cilt

35

Sayı

5

Künye

ÖZCAN E. Ö,MERCAN D,GÜRBÜZ N,ÇETİNKAYA E,ÇETİNKAYA B,ÖZDEMİR İ (2011). In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[$RuCl_2(p-cymene)]_2$ system for transfer hydrogenation reactions. Turkish Journal of Chemistry, 35(5), 699 - 709.