In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[RuCl_2(p-cymene)]_2 system for transfer hydrogenation reactions
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Dosyalar
Tarih
2011
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Turkish Journal of Chemistry
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Abstract: Hydrogen-transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity. In the present study novel ruthenium carbene complexes were generated in situ and tested for their transfer hydrogenation reactions. The in situ prepared 3 component 1,3- dialkyltetrahydropyrimidinium salts (LHX)/[RuCl2(p?cymene)]2 and KOH catalyzed quantitatively the transfer hydrogenation of ketones under mild reaction conditions in 2-propanol.
Açıklama
Anahtar Kelimeler
Kaynak
Turkish Journal of Chemistry
WoS Q Değeri
Scopus Q Değeri
Cilt
35
Sayı
5
Künye
ÖZCAN E. Ö,MERCAN D,GÜRBÜZ N,ÇETİNKAYA E,ÇETİNKAYA B,ÖZDEMİR İ (2011). In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[$RuCl_2(p-cymene)]_2$ system for transfer hydrogenation reactions. Turkish Journal of Chemistry, 35(5), 699 - 709.