Synthesis and use of mono- or bisxylyl linked bis(benzimidazolium) bromides as carbene precursors for C-C bond formation reactions

Küçük Resim Yok

Tarih

2008

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Elsevier Science Sa

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

Two benzimidazolium moieties linked by one or two xylyls (m- and p-) have been synthesized, characterized and then they were used for Heck coupling reactions as in situ formed catalysts. Mono bridged salts are more efficient as compared to bisbridged salts. In addition, mono bridged salts were converted to Rh-NHC complexes which were tested as catalysts for the arylation of aldehydes. (C) 2007 Elsevier B.V. All rights reserved.

Açıklama

Anahtar Kelimeler

bridged bisbenzimidazolium salts, catalytic activities, C-C coupling, rhodium complexes

Kaynak

Journal of Organometallic Chemistry

WoS Q Değeri

Q2

Scopus Q Değeri

Q3

Cilt

693

Sayı

3

Künye