A New Palladium Complex Containing the Mixture of Carbene and Phosphine Ligands: Synthesis, Crystal Structure and Spectral FT-IR, NMR and UV-Vis Researches
Küçük Resim Yok
Tarih
2019
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Chinese Journal Structural Chemistry
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In this paper, a new Pd-based complex that contains N-heterocyclic carbene (NHC) and triphenylphosphine (PPh3) ligands was synthesized. The cis-(NHC)PdBr2(PPh3) complex has been prepared by the substitution of 3-chloropyridine ligand in (NHC)PdBr2(3-chloropyridine) complex with triphenylphosphine. This complex has been characterized by using H-1 NMR, P-31 {H-1} NMR, C-13 {H-1} NMR, FTIR, UV-Vis spectroscopy and elemental analysis techniques. The molecular and crystal structures of the cis-(NHC)PdBr2(PPh3) complex were determined by single-crystal X-ray diffraction method.
Açıklama
Anahtar Kelimeler
FTIR, N-heterocyclic carbene, NMR, UV-VIS, X-ray diffraction
Kaynak
Chinese Journal of Structural Chemistry
WoS Q Değeri
Q4
Scopus Q Değeri
Q3
Cilt
38
Sayı
10
