N-[bis(2,4,6-trimethylphenoxy)phos-phinoyl]-P,P,P-tris(2,4,6-trimethyl-phenoxy)phosphazene
Küçük Resim Yok
Tarih
2000
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Int Union Crystallography
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The title compound, C45H55NO6P2, consists of an acyclic P=N-P(O) monophosphazene chain and five bulky 2,4,6-trimethylphenoxy side groups which predominantly determine the molecular shape. Although the P-N single [1.586 (3) Angstrom] and P=N double [1.517 (3) Angstrom] bonds are significantly different from each other, both are substantially shorter than the ideal P-N single bond. The P-N-P angle [146.0 (2)degrees] corresponds to the upper limit reported for acyclic phosphazene derivatives in the literature.
Açıklama
Anahtar Kelimeler
Phosphorus-Nitrogen-Compounds, Trichloro-N-Dichlorophosphorylmonophosphazene, Chain Linear Phosphazenes, Crystal-Structure, Side-Groups, Aminolysis, Cl2p(O).N=Pcl3, Conformation
Kaynak
Acta Crystallographica Section C-Structural Chemistry
WoS Q Değeri
N/A
Scopus Q Değeri
Q3
Cilt
56
