Synthesis, crystal structure, DFT studies and catalytic activity of an N-(2,2-dimethyl-1,3-dioxolane-4yl-methyl)benzimidazole ruthenium(II) hydrate complex

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dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridÖzdemir, Namık/0000-0003-3371-9874
dc.authoridOzdemir, Ismail/0000-0001-6325-0216
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidÖzdemir, Namık/J-6434-2015
dc.contributor.authorOzdemir, Namik
dc.contributor.authorKarabekmez, Funda Dogan
dc.contributor.authorKaraca, Emine Ozge
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:53:26Z
dc.date.available2024-08-04T20:53:26Z
dc.date.issued2023
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this study, the new N-coordinated benzimidazole ruthenium(II) complex was synthesized. The complex was fully characterized by FT-IR, 1 H and 13 C NMR spectroscopic methods. The molecular structure of the complex has been verified by X-ray crystallography. Besides, theoretical structure and spectroscopic data were obtained using density functional theory (DFT/HSEH1PBE) method with the cc-pVDZ basis set for C, H, N, O and Cl atoms, and the LANL2DZ basis set for the metal atom, and compared with the experimental data. This complex has also been tested for the N-alkylation of aromatic amines with arylmethyl alcohols under neat conditions in the presence of KOBut.(c) 2023 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.molstruc.2023.135159
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85148325248en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2023.135159
dc.identifier.urihttps://hdl.handle.net/11616/101178
dc.identifier.volume1281en_US
dc.identifier.wosWOS:000945999600001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectRutheniumen_US
dc.subjectCrystallographyen_US
dc.subjectDFTen_US
dc.subjectN-alkylationen_US
dc.titleSynthesis, crystal structure, DFT studies and catalytic activity of an N-(2,2-dimethyl-1,3-dioxolane-4yl-methyl)benzimidazole ruthenium(II) hydrate complexen_US
dc.typeArticleen_US

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