Optimization of process parameters at direct liquefaction of waste PETs

Basit Öğe Kaydı
dc.authoridolam, mikail/0000-0002-4153-1612
dc.authorwosidolam, mikail/CAG-0316-2022
dc.contributor.authorOlam, Mikail
dc.contributor.authorKaraca, Huseyin
dc.date.accessioned2024-08-04T20:53:06Z
dc.date.available2024-08-04T20:53:06Z
dc.date.issued2023
dc.departmentİnönü Üniversitesien_US
dc.description.abstractWaste polyethylene terephthalate (wPET) was converted to liquid fuel by direct liquefaction method. Addi-tionally, how the catalyst (sodium borohydride) and microwave pre-treatment affect the total conversion and the char yield were investigated. Direct liquefaction experiments were carried out in a batch reactor under non-catalytic/catalytic conditions, and reaction temperature of 325-425 degrees C, and solid/solvent ratio of 1/4, and reac-tion time of 15-90 min, and microwave pre-treatment time of 3-10 min, and an initial nitrogen pressure of 20 bar. Both the microwave pre-treatment and sodium borohydride (NaBH4) increased the total conversion in the direct liquefaction of wPETs. According to fourier transform infrared spectroscopy (FTIR) and X-Ray diffraction (XRD) analysis of char samples obtained in the direct liquefaction process, the NaBH4 was converted to sodium borate (Na2B8O13). NaBH4 made both hydrogen (H) donating and catalytic effect. The highest total conversion in direct liquefaction of wPETs, which has at the reaction time of 30 min, and the reaction temperature of 400 degrees C, and in presence of NaBH4, and the microwave pre-treatment of 3 and 8 min, was 62%. The optimum process parameters in direct liquefaction of wPETs are the reaction time of 30 min, and reaction temperature of 400 degrees C, and the microwave pre-treatment time of 3 min.en_US
dc.description.sponsorshipInonu University Scientific Research Projects Coordination Unit [FYL-2018-1176]en_US
dc.description.sponsorshipThis research was supported by Inonu University Scientific Research Projects Coordination Unit with project number FYL-2018-1176.en_US
dc.identifier.doi10.1016/j.psep.2022.10.058
dc.identifier.endpage994en_US
dc.identifier.issn0957-5820
dc.identifier.issn1744-3598
dc.identifier.scopus2-s2.0-85140979270en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage986en_US
dc.identifier.urihttps://doi.org/10.1016/j.psep.2022.10.058
dc.identifier.urihttps://hdl.handle.net/11616/100969
dc.identifier.volume171en_US
dc.identifier.wosWOS:000944487900001en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofProcess Safety and Environmental Protectionen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPET recyclingen_US
dc.subjectSodium borohydrideen_US
dc.subjectDirect liquefactionen_US
dc.subjectMicrowave pre-treateden_US
dc.subjectProcess parametersen_US
dc.subjectTotal conversionen_US
dc.subjectChar and oil yielden_US
dc.subjectCharacterizationen_US
dc.titleOptimization of process parameters at direct liquefaction of waste PETsen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu