N-heterocyclic carbene palladium complexes with different N-coordinated ligands: Comparison of their catalytic activities in Suzuki-Miyaura and Mizoroki-Heck reactions

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridKarataş, Mert Olgun/0000-0001-8500-2088
dc.authoridÖzdemir, Namık/0000-0003-3371-9874
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidKarataş, Mert Olgun/ABG-7848-2020
dc.authorwosidÖzdemir, Namık/J-6434-2015
dc.contributor.authorKaratas, Mert Olgun
dc.contributor.authorOzdemir, Namik
dc.contributor.authorAlici, Bulent
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:47:02Z
dc.date.available2024-08-04T20:47:02Z
dc.date.issued2020
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this paper, we have reported the synthesis and catalytic activities of four new anthracene substituted imidazole-based palladium N-heterocyclic carbene complexes. The synthesized complexes, 2a-d, were stabilized with different N-heterocycles, namely pyridine, N-methylimidazole, N-vinylimidazole and 4,5-dimethylthiazole, respectively. The complexes were completely characterized using H-1 NMR, C-13 NMR, IR, LC-MS spectroscopic methods and elemental analyses. The crystal structures of 2a, 2c and 2d were also reported. The catalytic activities of all the complexes were tested for Suzuki-Miyaura and Mizoroki-Heck cross-coupling reactions in aqueous medium. According to the results, for the Suzuki-Miyaura reaction, the pyridine bearing complex 2a, and for the Mizoroki-Heck reaction, the 4,5-dimethylthiazole bearing complex 2d were found to be the most active catalysts. (C) 2019 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipOndokuz Mayis University [PYO.FEN.1906.19.001]en_US
dc.description.sponsorshipThis study was supported by Ondokuz Mayis University (Project No.: PYO.FEN.1906.19.001).en_US
dc.identifier.doi10.1016/j.poly.2019.114271
dc.identifier.issn0277-5387
dc.identifier.scopus2-s2.0-85076679164en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.poly.2019.114271
dc.identifier.urihttps://hdl.handle.net/11616/99104
dc.identifier.volume176en_US
dc.identifier.wosWOS:000517658300023en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofPolyhedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPalladiumen_US
dc.subjectN-Heterocyclic carbeneen_US
dc.subjectSuzuki-Miyaura reactionen_US
dc.subjectMizoroki-Heck reactionen_US
dc.subjectCatalysisen_US
dc.titleN-heterocyclic carbene palladium complexes with different N-coordinated ligands: Comparison of their catalytic activities in Suzuki-Miyaura and Mizoroki-Heck reactionsen_US
dc.typeArticleen_US

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