Synthesis of new iron-NHC complexes as catalysts for hydrosilylation reactions

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridDüşünceli, Serpil Demir/0000-0001-8765-4039
dc.authoridSortais, Jean-Baptiste/0000-0003-1178-8588
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidDemir, Serpil/AAI-1740-2019
dc.authorwosidDüşünceli, Serpil Demir/AAA-7160-2021
dc.authorwosidSortais, Jean-Baptiste/B-3801-2014
dc.contributor.authorDemir, Serpil
dc.contributor.authorGokce, Yasemin
dc.contributor.authorKaloglu, Nazan
dc.contributor.authorSortais, Jean-Baptiste
dc.contributor.authorDarcel, Christophe
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:37:44Z
dc.date.available2024-08-04T20:37:44Z
dc.date.issued2013
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA series of new piano-stool iron(II) complexes comprising N-heterocyclic carbene ligands [Fe(Cp)(CO)2(NHC)]I (NHC = 1,3-disubstituted imidazolidin-2-ylidene) have been synthesized and analyzed by 1H NMR, 13C NMR, IR, elemental analysis and mass spectrometric techniques. These compounds were easily prepared from the reaction of disubstituted imidazolidin-2-ylidene with [FeI(Cp)(CO)2] in toluene at room temperature. These complexes were tested in the catalytic hydrosilylation reaction of aldehydes and ketones with phenylsilane in solvent-free conditions. After a basic hydrolysis step, the corresponding alcohols were obtained in good yields. Copyright (c) 2013 John Wiley & Sons, Ltd.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK; CNRS (France) [210T051]; Inonu University; Universite de Rennes 1, Rennes Metropole; Ministere de l'Enseignement Superieur et de la Rechercheen_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey TUBITAK, and the CNRS (France) [project 210T051] and Inonu University Research Fund. CD and JBS are grateful to the Universite de Rennes 1, Rennes Metropole and Ministere de l'Enseignement Superieur et de la Recherche for support.en_US
dc.identifier.doi10.1002/aoc.3006
dc.identifier.endpage464en_US
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-84880765418en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage459en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.3006
dc.identifier.urihttps://hdl.handle.net/11616/96149
dc.identifier.volume27en_US
dc.identifier.wosWOS:000325923800005en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectironen_US
dc.subjectNHC ligandsen_US
dc.subjecthydrosilylationen_US
dc.subjectaldehydesen_US
dc.subjectketonesen_US
dc.titleSynthesis of new iron-NHC complexes as catalysts for hydrosilylation reactionsen_US
dc.typeReview Articleen_US

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