Postgrafting of Congo red dye onto hyperbranched mesoporous silica with terminal amino groups

Basit Öğe Kaydı
dc.authoridGultek, Ahmet/0000-0002-4980-1568
dc.authorwosidGultek, Ahmet/AAG-5735-2019
dc.contributor.authorSeçkin, T
dc.contributor.authorGültek, A
dc.date.accessioned2024-08-04T20:13:51Z
dc.date.available2024-08-04T20:13:51Z
dc.date.issued2003
dc.departmentİnönü Üniversitesien_US
dc.description.abstractCongo red dye has been postgrafted onto mesoporous silica that was prepared by the controlled hydrolysis of tetraethyl orthosilicate in the presence of organic agents. Surface grafting of mesoporous silica having amino groups as initiator sites was prepared from gamma-aminopropyl-trimethoxysilane by sol-gel process. The postgraffing reaction of Congo red onto silica with terminal amino groups was achieved by a repeated step of the addition of methyl acrylate to amine groups followed by the amidation of the resulting ester moieties with ethylene diamine. Postgrafting efficiency of all materials has been outlined. Because postgrafting efficiency values have been found to be smaller than theoretical values, it is concluded that the resulting product was more likely to be a hyperbranched polymer rather than a true dendrimer at higher generations. The postgrafted structures with amino-terminal groups provide an attractive site for binding Congo red dye that not only persists in its characteristic properties, but also has exceptional hybrid properties possessed by mesoporous silica. (C) 2003 Wiley Periodicals, Inc.en_US
dc.identifier.doi10.1002/app.13149
dc.identifier.endpage3911en_US
dc.identifier.issn0021-8995
dc.identifier.issue14en_US
dc.identifier.scopus2-s2.0-17344392557en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage3905en_US
dc.identifier.urihttps://doi.org/10.1002/app.13149
dc.identifier.urihttps://hdl.handle.net/11616/93886
dc.identifier.volume90en_US
dc.identifier.wosWOS:000186374700019en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherJohn Wiley & Sons Incen_US
dc.relation.ispartofJournal of Applied Polymer Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectpigmentsen_US
dc.subjectnanocompositesen_US
dc.subjecthyperbrancheden_US
dc.subjectsilicasen_US
dc.titlePostgrafting of Congo red dye onto hyperbranched mesoporous silica with terminal amino groupsen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu