Optimization of Electrochemical Presodiation Parameters of Na-Ion Full Cells for Stable Solid-Electrolyte Interface Formation: Hard Carbon Rods from Waste Firefighter Suits

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dc.authoridBulut, Fatih/0000-0001-6603-2468
dc.authoridALTUNDAĞ, Sebahat/0000-0002-4777-8376
dc.authoridyalman, emine/0000-0002-1782-3543
dc.authoridALTIN, Serdar/0000-0002-4590-907X;
dc.authorwosidBulut, Fatih/F-7201-2013
dc.authorwosidALTUNDAĞ, Sebahat/AAB-4167-2021
dc.authorwosidyalman, emine/ACE-9948-2022
dc.authorwosidALTIN, Serdar/H-4880-2014
dc.authorwosidDepci, Tolga/A-2867-2016
dc.authorwosidAydın, Mustafa Göktan/JVO-0306-2024
dc.contributor.authorYalman, Emine
dc.contributor.authorAltundag, Sebahat
dc.contributor.authorAydin, Mustafa Goktan
dc.contributor.authorOnal, Yunus
dc.contributor.authorDepci, Tolga
dc.contributor.authorTekbas, Hasan
dc.contributor.authorBulut, Fatih
dc.date.accessioned2024-08-04T20:53:34Z
dc.date.available2024-08-04T20:53:34Z
dc.date.issued2023
dc.departmentİnönü Üniversitesien_US
dc.description.abstractUtilizing the synthetic waste of firefighter costumes, rod-shaped hard carbon materials are effectively produced for the first time with over 99% purity, and their structural properties are evaluated using the appropriate spectroscopic techniques. The galvanostatic cycling tests are performed at different temperatures and the result shows that the capacity and capacity fade values are directly affected by the temperature. The high-rate consumption of sodium ions during the evolution of the solid-electrolyte interface in the first cycle of the cells is observed and the highest capacity of the half cells is obtained as 410 and 233 mAh g(-1) for the first and second cycles, respectively. To compensate for the sodium-ion loss, an electrochemical treatment presodiation technique is implemented, which is an effective means of compensating for the initial inefficiency. The optimum presodiation condition of electrochemical treatment of anode electrode for the production of Na0.67Mn0.5Fe0.45Ti0.07O2/presodiated hard carbon full cells is investigated. The highest capacity values for C/10 are obtained at 114.9 mAh g(-1) for the full cells using the voltage window of 2-4 V. The cost analysis of the battery pack for 90 kW electric-powered cars is calculated by the BatPaC software and the results are evaluated for possible commercialization.en_US
dc.description.sponsorshipInonu University Research Council [FYL-2021-2437]en_US
dc.description.sponsorshipAcknowledgements S.A. and H.T. would like to thank Inonu University Research Council for project number FYL-2021-2437.en_US
dc.identifier.doi10.1002/ente.202300014
dc.identifier.issn2194-4288
dc.identifier.issn2194-4296
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-85151380410en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1002/ente.202300014
dc.identifier.urihttps://hdl.handle.net/11616/101266
dc.identifier.volume11en_US
dc.identifier.wosWOS:000961475900001en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofEnergy Technologyen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectBatPaCen_US
dc.subjecthard carbonen_US
dc.subjectNa-ion full cellsen_US
dc.subjectpre-sodiationen_US
dc.titleOptimization of Electrochemical Presodiation Parameters of Na-Ion Full Cells for Stable Solid-Electrolyte Interface Formation: Hard Carbon Rods from Waste Firefighter Suitsen_US
dc.typeArticleen_US

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