Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion

dc.contributor.authorYiğit, Murat
dc.contributor.authorSeçkin, Turgay
dc.contributor.authorKöytepe, Süleyman
dc.contributor.authorÇetinkaya, Engin
dc.date.accessioned2020-11-11T07:29:01Z
dc.date.available2020-11-11T07:29:01Z
dc.date.issued2007
dc.departmentİnönü Üniversitesien_US
dc.description.abstractAbstract: This paper presents the synthesis and characterization of polyimides containing a chiral (R,R)or (S,S) 1,3-bis(p-N,N'-dimethylaminobenzyl)-perhydrobenzimidazol-2-thion unit in the backbone.The reactions occur between equimolar amounts of a dianhydride and an aromatic dimethylamine in the presence of the solvent N-methyl-2-pyrollidone (NMP). In this work, the chiral monomer RR and SS -1,3-bis(p -N,N'-dimethylaminobenzyl)-perhydrobenzimidazol-2-thion were used as diamines. The polyimides obtained were characterized by thermogravimetry (TGA), differential thermal analysis (DTA), differential scanning calorimeter (DSC), infrared spectroscopy (FT-IR), and gel permeation chromatography (GPC). It was found that the composition of the polymer had a significant effect upon the thermal behavior of the material.en_US
dc.identifier.citationYİĞİT M,SEÇKİN T,KÖYTEPE S,ÇETİNKAYA E (2007). Synthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thion. Turkish Journal of Chemistry, 31(2), 113 - 124.en_US
dc.identifier.endpage124en_US
dc.identifier.issn1300-0527
dc.identifier.issn1303-6130
dc.identifier.issue2en_US
dc.identifier.startpage113en_US
dc.identifier.trdizinid67287en_US
dc.identifier.urihttps://hdl.handle.net/11616/18722
dc.identifier.urihttps://search.trdizin.gov.tr/yayin/detay/67287
dc.identifier.volume31en_US
dc.indekslendigikaynakTR-Dizinen_US
dc.language.isotren_US
dc.publisherTurkish Journal of Chemistryen_US
dc.relation.ispartofTurkish Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.titleSynthesis and characterization of polyimides prepared from optically active (R,R) and (S,S)-1,3-bis (p-N,N'- dimethylaminobenzyl)-perhydrobenzimidazol-2-thionen_US
dc.typeArticleen_US

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