Synthesis and characterization of novel polyacrylate-clay sol-gel materials

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dc.authoridÖnal, Yunus/0000-0001-6342-6816
dc.authorwosidÖnal, Yunus/E-7170-2018
dc.contributor.authorSeckin, T
dc.contributor.authorOnal, Y
dc.contributor.authorAksoy, I
dc.contributor.authorYakinci, ME
dc.date.accessioned2024-08-04T20:11:51Z
dc.date.available2024-08-04T20:11:51Z
dc.date.issued1996
dc.departmentİnönü Üniversitesien_US
dc.description.abstractOrgano-functional silanes which were able to form chemical bonds with kaolinite and could also have an affinity to the materials of concern here, were studied by the sol-gel process. Polymethacrylate with trialkoxy silyl functional groups were prepared, hydrolysed and co-condensed with kaolinite. The progress of the hydrolysis, which proceeded very slowly, was followed by Karl-Fischer titration. Thermal behavior was investigated by differential thermal analysis. The extent of the reaction leading to network formation was qualitatively followed by Fourier transform-infrared spectroscopy and X-ray diffraction. Free-radical polymerization was carried out ultrasonically in the presence of a catalyst. Trimethoxy silane end-capped silane was found to be covalently bonded to kaolinite. The copolymers, with various amounts of kaolinite, were then hydrolysed and co-condensed in the presence of a catalyst to yield sol-gel materials which have a controllable combination of properties of both the polymer and kaolinite.en_US
dc.identifier.doi10.1007/BF00354657
dc.identifier.endpage3127en_US
dc.identifier.issn0022-2461
dc.identifier.issue12en_US
dc.identifier.scopus2-s2.0-0030169997en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage3123en_US
dc.identifier.urihttps://doi.org/10.1007/BF00354657
dc.identifier.urihttps://hdl.handle.net/11616/93038
dc.identifier.volume31en_US
dc.identifier.wosWOS:A1996UV97600010en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherChapman Hall Ltden_US
dc.relation.ispartofJournal of Materials Scienceen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectStructure Property Behavioren_US
dc.subjectHybrid Materialsen_US
dc.subjectSilaneen_US
dc.subjectSilicaen_US
dc.titleSynthesis and characterization of novel polyacrylate-clay sol-gel materialsen_US
dc.typeArticleen_US

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