In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[RuCl2(p-cymene)]2 system for transfer hydrogenation reactions
Küçük Resim Yok
Tarih
2011
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Tubitak Scientific & Technological Research Council Turkey
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Hydrogen-transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity. In the present study novel ruthenium carbene complexes were generated in situ and tested for their transfer hydrogenation reactions. The in situ prepared 3 component 1,3-dialkyltetrahydropyrimidinium salts (LHX)/[RuCl2(p-cymene)](2) and KOH catalyzed quantitatively the transfer hydrogenation of ketones under mild reaction conditions in 2-propanol.
Açıklama
Anahtar Kelimeler
Ruthenium, tetrahydropyrimidin-2-ylidene, N-heterocyclic carbene, transfer hydrogenation, ketone
Kaynak
Turkish Journal of Chemistry
WoS Q Değeri
Q3
Scopus Q Değeri
N/A
Cilt
35
Sayı
5
