Unusual products in the reactions of hexachlorocyclotriphosphazatriene with sodium aryloxides

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dc.authoridHokelek, Tuncer/0000-0002-8602-4382
dc.authoridBegeç, Saliha/0000-0001-5331-6736
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authoridKILIC, ADEM/0000-0003-2181-2457
dc.authorwosidHokelek, Tuncer/JCE-0691-2023
dc.authorwosidHokelek, Tuncer/G-6068-2013
dc.authorwosidBegeç, Saliha/AAA-9708-2021
dc.contributor.authorKilic, A
dc.contributor.authorBegec, S
dc.contributor.authorCetinkaya, B
dc.contributor.authorHokelek, T
dc.contributor.authorKilic, Z
dc.contributor.authorGunduz, N
dc.contributor.authorYildiz, M
dc.date.accessioned2024-08-04T20:11:45Z
dc.date.available2024-08-04T20:11:45Z
dc.date.issued1996
dc.departmentİnönü Üniversitesien_US
dc.description.abstractReactions of hexachlorocyclotriphosphazatriene, N3P3Cl6 1, with sodium aryloxides have been studied. Compound 1 was found to react by the nucleophilic substitution path way to yield monocyclophosphazenes [N3P3Cl5(OC(6)H(2)Bu(3)(t)-2, 4, 6) 5 and N3P3Cl4(OC(6)H(2)Me-4-Bu(2)(t)-2, 6)(2) 6] and bi(cyclophosphazenes) ([Cl5N3P3-P3N3Cl4(OC(6)H(3)Bu(2)(t)-2, 6)] 7 and [N3P3(OC(6)H(3)Bu(2)(t)-2, 6)(5)](2) 8]. The unusual bi(cyclophosphazenes) 7 and 8 are the first examples of two cyclotriphosphazene rings linked by a P-P bond [2.193 (2) Angstrom], which have been obtained by reacting 1 with ArONa. The structures of compounds 5-8 ave ascertained by elemental analyses, H-1-, P-31-C-13-NMR, IR, and MS spectra. The molecular structure of monocyclic-phosphazene 5 was determined by X-ray diffraction techniques for further structural assignment. It crystallizes in the monoclinic space group P2(1)/m with a = 6.144(2), b = 17.079(9), c = 13.181(9) Angstrom, beta = 92.79(7), and Z = 2, R = 0.074. Compound 5 is on a crystallographic mirror plane, and there is only a half molecule in the asymmetric unit. (C) 1996 John Wiley & Sons, Inc.en_US
dc.identifier.doi10.1002/(SICI)1098-1071(199608)7:4<249
dc.identifier.endpage256en_US
dc.identifier.issn1042-7163
dc.identifier.issn1098-1071
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-0000883213en_US
dc.identifier.scopusqualityQ4en_US
dc.identifier.startpage249en_US
dc.identifier.urihttps://doi.org/10.1002/(SICI)1098-1071(199608)7:4<249
dc.identifier.urihttps://hdl.handle.net/11616/92974
dc.identifier.volume7en_US
dc.identifier.wosWOS:A1996UX83500005en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofHeteroatom Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPhosphorus-Nitrogen-Compoundsen_US
dc.subjectX-Ray Structureen_US
dc.subjectReagentsen_US
dc.subjectCrystalen_US
dc.subjectSpectroscopyen_US
dc.subjectPhosphazenesen_US
dc.subjectDerivativesen_US
dc.subjectMechanismen_US
dc.titleUnusual products in the reactions of hexachlorocyclotriphosphazatriene with sodium aryloxidesen_US
dc.typeArticleen_US

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