Suzuki reaction of aryl chlorides using saturated N-heterocarbene ligands
Küçük Resim Yok
Tarih
2005
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
John Wiley & Sons Inc
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
From readily available starting materials, six 1,3-dialkly-imidazolinium bromides (2a-f) have been prepared and characterized by conventional spectroscopic methods and elemental analyses. The incorporation of saturated N-heterocyclic carbenes into palladium precatalysts gives high catalyst activity in the Suzuki coupling of deactivated aryl chloride substrates in aqueous media. The complexes were generated in the presence of Pd(OAC)(2) by in situ deprotonation of 2a-f. (c) 2005 Wiley Periodicals, Inc.
Açıklama
Anahtar Kelimeler
Cross-Coupling Reactions, Arylboronic Acids, Efficient Catalysts, Carbene Complexes, Stable Carbenes, Aqueous-Media, Halides, Heck, Palladacycles, Palladium(Ii)
Kaynak
Heteroatom Chemistry
WoS Q Değeri
Q3
Scopus Q Değeri
N/A
Cilt
16
Sayı
7
