Acetalization and transacetalization reactions catalyzed by ruthenium, rhodium, and iridium complexes with (2-{{bis[3-(trifluoromethyl)phenyl]phosphino}methyl}-2-methylpropane-1,3-diyl}bis[bis[3-(trifluoromethyl)phenyl]phosphine] (MeC[CH2P(m-CF3C6H4)2]3)

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dc.authorwosidSÜLÜ, Mustafa/ABH-5282-2020
dc.contributor.authorSülü, M
dc.contributor.authorVenanzi, LM
dc.date.accessioned2024-08-04T20:12:16Z
dc.date.available2024-08-04T20:12:16Z
dc.date.issued2001
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe complexes [RhCl(3 n)(MeCN)(n)(CF(3)triphos)](CF3SO3)(n) (n = 1, 2; CF(3)triphos = MeC[CH2P(m-CF3C6H4)(2)](3)) and [M(MeCN)(3) (CF(3)triphos)](CF3SO3)(n) (M = Ru, n = 2; M = Ir, n = 3) are catalyst precursors for some typical acetalization and transacetalization reactions. The activity of these complexes is higher than those of the corresponding species containing the parent ligand MeC[CH2P(C6H5)(2)](3)(Htriphos). Also the complexes [MCl3(tripod)] (tripod = Htriphos and CF(3)triphos) are active catalysts for the above reactions. The complex [RhCl2(MeCN)(CF(3)triphos)](CF3SO3) catalyzes the acetalization of benzophenone.en_US
dc.identifier.doi10.1002/1522-2675(20010418)84:4<898
dc.identifier.endpage907en_US
dc.identifier.issn0018-019X
dc.identifier.issn1522-2675
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-0035047343en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage898en_US
dc.identifier.urihttps://doi.org/10.1002/1522-2675(20010418)84:4<898
dc.identifier.urihttps://hdl.handle.net/11616/93310
dc.identifier.volume84en_US
dc.identifier.wosWOS:000168618400015en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofHelvetica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRay Crystal-Structureen_US
dc.subjectCoordination Chemistryen_US
dc.subjectExchangeen_US
dc.subjectAcetalsen_US
dc.subjectTriphosen_US
dc.titleAcetalization and transacetalization reactions catalyzed by ruthenium, rhodium, and iridium complexes with (2-{{bis[3-(trifluoromethyl)phenyl]phosphino}methyl}-2-methylpropane-1,3-diyl}bis[bis[3-(trifluoromethyl)phenyl]phosphine] (MeC[CH2P(m-CF3C6H4)2]3)en_US
dc.typeArticleen_US

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