Synthesis of silver(I) and palladium(II) N-heterocyclic carbene complexes and their use as catalysts for the direct C5 arylation of heteroaromatic compounds

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorYigit, Beyhan
dc.contributor.authorYigit, Murat
dc.contributor.authorDagdeviren, Zeynep
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:41:51Z
dc.date.available2024-08-04T20:41:51Z
dc.date.issued2016
dc.departmentİnönü Üniversitesien_US
dc.description.abstractSilver(I) N-heterocyclic carbene complexes were synthesized in good yields by the reactions of 1,3-dialkylperhydrobenzimidazolium salts with silver(I) oxide in dichloromethane. The silver complexes were used as carbene-transfer agents to synthesize palladium(II) N-heterocyclic carbene complexes. All of the complexes were characterized by physicochemical and spectroscopic methods. The new palladium complexes were tested as catalysts in the direct C5 arylation of 2-n-butylfuran, 2-n-butylthiophene and 2-n-propylthiazole with aryl bromides at 130 A degrees C in N,N-dimethylacetamide. The arylation reactions proceeded selectively at the C5 position of the heteroaromatic compounds, and the corresponding coupling products were obtained in moderate to good yields by using 0.5 mol% of the palladium complex.en_US
dc.description.sponsorshipAdiyaman University [FEFMAP/2015-0004]en_US
dc.description.sponsorshipWe thank the Adiyaman University Research Fund (FEFMAP/2015-0004) for financial support of this work.en_US
dc.identifier.doi10.1007/s11243-016-0075-y
dc.identifier.endpage757en_US
dc.identifier.issn0340-4285
dc.identifier.issn1572-901X
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-84976507292en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage751en_US
dc.identifier.urihttps://doi.org/10.1007/s11243-016-0075-y
dc.identifier.urihttps://hdl.handle.net/11616/97390
dc.identifier.volume41en_US
dc.identifier.wosWOS:000382876000003en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofTransition Metal Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectTransfer Hydrogenationen_US
dc.subjectThiopheneen_US
dc.subjectLigandsen_US
dc.subjectFuranen_US
dc.subjectFunctionalizationen_US
dc.subjectActivationen_US
dc.subjectAminationen_US
dc.subjectChloridesen_US
dc.subjectOlefinen_US
dc.subjectAg(I)en_US
dc.titleSynthesis of silver(I) and palladium(II) N-heterocyclic carbene complexes and their use as catalysts for the direct C5 arylation of heteroaromatic compoundsen_US
dc.typeArticleen_US

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