KINETIC MODEL FOR DISSOLUTION OF CEMENT COPPER IN SULFURIC ACID SOLUTIONS CONTAINING CUPRIC IONS
Küçük Resim Yok
Tarih
2021
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Lviv Polytech Natl Univ
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
In this paper, the dissolution kinetics of cement copper powder in sulfuric acid solutions containing cupric ions was examined. It was observed that the dissolution rate of copper increased with increasing the acid concentration, temperature, and stirring speed. It was determined that the dissolution rate of copper enhanced with increasing the cupric ion concentration up to 0.025 M. It was found that the temperature and concentration of cupric ion had more considerable effects on the dissolution of copper powder. The kinetic analysis of the process was performed, and it was observed that it fits the first order pseudo-homogenous reaction model. The activation energy was calculated to be 31.1 kJ/mol.
Açıklama
Anahtar Kelimeler
malachite, cement copper, cupric ion, dissolution, kinetics
Kaynak
Chemistry & Chemical Technology
WoS Q Değeri
N/A
Scopus Q Değeri
Q3
Cilt
15
Sayı
3