Novel ruthenium(II)-N-heterocyclic carbene complexes; synthesis, characterization and catalytic application

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dc.authoridYaşar, Sedat/0000-0001-7285-2761
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridkaraca, emine özge/0000-0003-2094-9742
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authorwosidYaşar, Sedat/ABG-8356-2020
dc.authorwosidSahin, Onur/KGM-3910-2024
dc.authorwosidkaraca, emine özge/AAH-2535-2019
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorYasar, Sedat
dc.contributor.authorKaraca, Emine Ozge
dc.contributor.authorSahin, Caglar
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorSahin, Onur
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2024-08-04T20:40:13Z
dc.date.available2024-08-04T20:40:13Z
dc.date.issued2015
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe synthesis of highly active ruthenium(II) catalyst based on N-heterocyclic carbene (NHC) bearing alkyl and aryl groups is reported. The complexes are easily handled in very good yields via synthesis of silver -NHC complexes and subsequent reaction with [RuCl2(p-cymene)](2) in dichloromethane (DCM) under N-2 condition. All new compounds were characterized by LC-MSMS, elemental analysis, NMR spectroscopy and X-ray diffraction. With the development of a more efficient catalytic system for transfer hydrogenation of aryl ketones and aldehydes in mind, the catalytic performance of the Ru-NHC complexes for transfer hydrogenation was investigated. (c) 2015 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipInonu University Research Fund [BAP gudumlu:2014-54]en_US
dc.description.sponsorshipThis work was financially supported by Inonu University Research Fund (BAP gudumlu:2014-54)en_US
dc.identifier.doi10.1016/j.jorganchem.2015.04.012
dc.identifier.endpage7en_US
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.scopus2-s2.0-84929322166en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage1en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2015.04.012
dc.identifier.urihttps://hdl.handle.net/11616/96785
dc.identifier.volume789-790en_US
dc.identifier.wosWOS:000355851000001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectTransfer hydrogenation reactionen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectRuthenium-NHC complexen_US
dc.subjectSilveren_US
dc.titleNovel ruthenium(II)-N-heterocyclic carbene complexes; synthesis, characterization and catalytic applicationen_US
dc.typeArticleen_US

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