Obtaining the best temperature parameters for co-carbonization of lignite (yatagan)-biomass (peach seed shell) by structural characterization

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dc.authoridKaraca, Huseyin/0000-0002-0543-8947
dc.authoridgunduz, figen/0000-0003-3455-3706
dc.authorwosidKaraca, Huseyin/ABG-8103-2020
dc.authorwosidgunduz, figen/ITV-5757-2023
dc.contributor.authorGunduz, Figen
dc.contributor.authorAkbulut, Yeliz
dc.contributor.authorKoyunoglu, Cemil
dc.contributor.authorOnal, Yunus
dc.contributor.authorKaraca, Huseyin
dc.date.accessioned2024-08-04T20:53:02Z
dc.date.available2024-08-04T20:53:02Z
dc.date.issued2022
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this study, Yatagan lignite (YL) and peach kernel shells (PKS) were originally taken separately and in a 1: 1 ratio by weight. Experiments were carried out in a 3-zone heated cylindrical furnace in a steel reactor. Structural characterization of all the solid products obtained was made by FTIR, XRD, and SEM analysis. When the FTIR and XRD spectra of the raw samples are examined, it is seen that they are rich in functional groups. It is seen that the PKS has aliphatic and aromatic structures and cellulosic structure -OH stresses (3500 cm(-1)). The sharp peak around 2918 cm(-1) in Yatagan lignite belongs to the aliphatic C-H stretch. In the XRD spectrum, it is seen that both structures are largely amorphous. The raw PKS contains 3 different amorphous macromolecular structures. Yatagan lignite, on the other hand, contains crystalline peaks of clay and inorganic structures, depending on the ash content, as well as the amorphous structure. As the temperature increases depending on the carbonization temperature, as seen in the FTIR spectrum, the peaks of the functional groups decrease and disappear with the disruption of small macromolecular structures. As a result of the structural adjustment with the temperature increase, M-O-M peaks around 1000 cm(-1) remain due to the aromatic C-H stretching and ash content. The paper centers around test assurance of operating temperatures in the consuming layer during co-carbonization. It is obtained that 800 degrees C is the best temperature condition for the co-carbonization process. It has been concluded that the chars obtained as a result of pyrolysis will be used as a solid fuel in both environmental (the lowest sulfur content) and economic (400 degrees C) sense. However, the fact that it has a very low sulfur content with the increase in the liquid and gas efficiency obtained at high temperatures again proves the production of an environmentally friendly liquid fuel.en_US
dc.identifier.doi10.1016/j.heliyon.2022.e10636
dc.identifier.issn2405-8440
dc.identifier.issue9en_US
dc.identifier.pmid36158104en_US
dc.identifier.scopus2-s2.0-85138585126en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.1016/j.heliyon.2022.e10636
dc.identifier.urihttps://hdl.handle.net/11616/100905
dc.identifier.volume8en_US
dc.identifier.wosWOS:000862374900015en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherCell Pressen_US
dc.relation.ispartofHeliyonen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectLigniteen_US
dc.subjectBiomassen_US
dc.subjectPeach kernel shellen_US
dc.subjectPyrolysisen_US
dc.subjectPyrolysis productsen_US
dc.subjectYielden_US
dc.subjectCharacterizationen_US
dc.titleObtaining the best temperature parameters for co-carbonization of lignite (yatagan)-biomass (peach seed shell) by structural characterizationen_US
dc.typeArticleen_US

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