Palladium Complexes with Tetrahydropyrimidin-2-ylidene Ligands: Catalytic Activity for the Direct Arylation of Furan, Thiophene, and Thiazole Derivatives

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridkaraca, emine özge/0000-0003-2094-9742
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridDoucet, Henri/0000-0002-1410-3663
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authoridyasar, sedat/0000-0001-7285-2761
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidkaraca, emine özge/AAH-2535-2019
dc.authorwosidSahin, Onur/KGM-3910-2024
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.contributor.authorKaraca, Emine Ozge
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorDoucet, Henri
dc.contributor.authorSahin, Onur
dc.contributor.authorBuyukgungor, Orhan
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2024-08-04T20:40:20Z
dc.date.available2024-08-04T20:40:20Z
dc.date.issued2015
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe synthesis and characterization of novel 1,3-benzyl-3,4,5,6-tetrahydropyrimidin-2-ylidene-based N-hetero-cyclic carbene palladium(II) complexes (1a-d) were described. The crystal structure of trans-dichlorobis[1,3-bis(4-methylbenzyl)-3,4,5,6-tetrahydropyrimidin-2-ylidend- palladium(II) was presented. Pd(II) complexes 1a-d were tested as catalysts in the direct C5 or C2 arylation of furans, thiophenes, and thiazoles, with various aryl bromides at 150 degrees C for 1 h. These complexes exhibited moderate to high catalytic activities under the given conditions.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK-BOSPHORUS (France) [109T605]; TUBA; Inonu University Research Fund [I.U. B.A.P: 2013/51]en_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey TUBITAK-BOSPHORUS (France) [109T605], TUBA, and Inonu University Research Fund (I.U. B.A.P: 2013/51).en_US
dc.identifier.doi10.1021/om501201r
dc.identifier.endpage2493en_US
dc.identifier.issn0276-7333
dc.identifier.issn1520-6041
dc.identifier.issue11en_US
dc.identifier.scopus2-s2.0-84935870521en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage2487en_US
dc.identifier.urihttps://doi.org/10.1021/om501201r
dc.identifier.urihttps://hdl.handle.net/11616/96859
dc.identifier.volume34en_US
dc.identifier.wosWOS:000356841800051en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofOrganometallicsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-Heterocyclic-Carbeneen_US
dc.subjectC-H Functionalizationen_US
dc.subjectCross-Coupling Reactionsen_US
dc.subjectDirect C-2 Arylationen_US
dc.subjectBond Formationen_US
dc.subjectAryl Halidesen_US
dc.subjectRoom-Temperatureen_US
dc.subjectAzolesen_US
dc.subjectEfficienten_US
dc.subjectChloridesen_US
dc.titlePalladium Complexes with Tetrahydropyrimidin-2-ylidene Ligands: Catalytic Activity for the Direct Arylation of Furan, Thiophene, and Thiazole Derivativesen_US
dc.typeArticleen_US

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