Rhodium-benzimidazolidin-2-ylidene catalyzed addition of arylboronic acids to aldehydes
Küçük Resim Yok
Tarih
2005
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Six rhodium-carbene complexes (2a-f) have been prepared and the new compounds characterized by C, H, N analyses, H-1-n.m.r. and C-13-n.m.r. Phenylboronic acid reacts with aldehydes in the presence of a catalytic amount of rhodium(I)-carbene complex, RhCl(COD)(1,3-dialkylbenzimidazolidin-2-ylidene), (2a-f), to give the corresponding aryl secondary alcohols in good yields.
Açıklama
Anahtar Kelimeler
Heterocyclic Carbene Complexes, Transition-Metal-Complexes, Alkene Metathesis, Rhodium, Palladium, Cross, Generation, Olefins
Kaynak
Transition Metal Chemistry
WoS Q Değeri
Q3
Scopus Q Değeri
Q2
Cilt
30
Sayı
3
