Synthesis of Quinoxaline-Linked Bis(Benzimidazolium) Salts and Their Catalytic Application in Palladium-Catalyzed Direct Arylation of Heteroarenes

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dc.authoridKaloğlu, Murat/0000-0002-2770-5532
dc.authorwosidKaloğlu, Murat/AAA-3956-2021
dc.contributor.authorKaloglu, Murat
dc.contributor.authorSahan, Mehmet Hanifi
dc.contributor.authorDusunceli, Serpil Demir
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:50:41Z
dc.date.available2024-08-04T20:50:41Z
dc.date.issued2022
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this study, quinoxaline-linked bis(benzimidazolium) salts were synthesized as bis-N-heterocyclic carbene (NHC) precursors. These bis(NHC) precursors were used as multidentate ligands for the construction of bi(hetero)aryls by palladium-catalyzed direct C-H activation process. The in situ prepared palladium complexes by mixtures of the Pd(OAc)(2) and the bis(NHC) precursors were used as the catalyst for direct C-H activation of heteroarenes. These catalytic system exhibited a modest catalytic activity in the direct C-H activation of five-membered heteroarenes with a wide range of (hetero)aryl bromides.en_US
dc.description.sponsorshipInonu University Research Fund (I.U.B.A.P. Project) [FYL-2020-2093]en_US
dc.description.sponsorshipSupport of Inonu University Research Fund (I.U.B.A.P. Project No: FYL-2020-2093) is gratefullyen_US
dc.identifier.doi10.1007/s10562-021-03787-2
dc.identifier.endpage2024en_US
dc.identifier.issn1011-372X
dc.identifier.issn1572-879X
dc.identifier.issue7en_US
dc.identifier.scopus2-s2.0-85114614202en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage2012en_US
dc.identifier.urihttps://doi.org/10.1007/s10562-021-03787-2
dc.identifier.urihttps://hdl.handle.net/11616/100197
dc.identifier.volume152en_US
dc.identifier.wosWOS:000694558000003en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofCatalysis Lettersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-Heterocyclic carbeneen_US
dc.subjectQuinoxalineen_US
dc.subjectMultidentate liganden_US
dc.subjectPalladiumen_US
dc.subjectCatalysisen_US
dc.subjectDirect arylationen_US
dc.subjectHeteroareneen_US
dc.titleSynthesis of Quinoxaline-Linked Bis(Benzimidazolium) Salts and Their Catalytic Application in Palladium-Catalyzed Direct Arylation of Heteroarenesen_US
dc.typeArticleen_US

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