Synthesis and stimuli-responsive properties of the phenanthroline based metallo-supramolecular polymers

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dc.authoridGultek, Ahmet/0000-0002-4980-1568
dc.authoridDemirel, Maruf Hursit/0000-0002-1274-407X
dc.authoridSEÇKİN, Turgay/0000-0001-8483-7366
dc.authoridKoytepe, Suleyman/0000-0002-4788-278X
dc.authorwosidGultek, Ahmet/AAG-5735-2019
dc.authorwosidDemirel, Maruf Hursit/W-7633-2018
dc.authorwosidSEÇKİN, Turgay/ABG-7537-2020
dc.authorwosidKöytepe, Süleyman/AAA-4168-2021
dc.contributor.authorDemirel, Maruf Hursit
dc.contributor.authorKoytepe, Suleyman
dc.contributor.authorGultek, Ahmet
dc.contributor.authorSeckin, Turgay
dc.date.accessioned2024-08-04T20:39:39Z
dc.date.available2024-08-04T20:39:39Z
dc.date.issued2014
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA series of functional metallo-supramolecular materials based on polyhedral oligomeric silsesquioxane (POSS) and phenanthroline ligand were prepared using a two-step approach. Firstly, using a phenanthroline ligand, an amino-functionalized transition metal complex was prepared by tin(II) chloride. In the second step, this metal complex was subsequently reacted with the octakis(3-chloropropyl)octasilsesquioxane, resulting for the metallosupramolecular polymers bearing POSS structure. All the synthesized compounds were fully characterized by spectroscopic analysis, thermal and electron microscopy techniques. Stimuli responsible properties of metallo-supramolecular materials were also investigated the reversibility upon external factors, such as electrochemical or the addition of competitive complexing ligands by electroanalytic techniques and UV-Vis spectroscopy. The electro- and chemo-responsive properties of the metallo-supramolecular materials were also improved. As a result, prepared phenanthroline-functionalized polyhedral silsesquioxane are good candidates for electronic, opto-electronic, and photovoltaic applications as a smart stimuli-responsive material.en_US
dc.description.sponsorshipTUBITAK - The Scientific and Technological Research Council of Turkey [MAG110M751]en_US
dc.description.sponsorshipAuthors would like to thank TUBITAK - The Scientific and Technological Research Council of Turkey for the financial support with the project number MAG110M751.en_US
dc.identifier.doi10.1007/s10965-013-0345-8
dc.identifier.issn1022-9760
dc.identifier.issn1572-8935
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-84897606429en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1007/s10965-013-0345-8
dc.identifier.urihttps://hdl.handle.net/11616/96397
dc.identifier.volume21en_US
dc.identifier.wosWOS:000329626200001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Polymer Researchen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSupramolecular polymersen_US
dc.subjectStimuli-responsive polymersen_US
dc.subjectPOSSen_US
dc.subjectPhenanthroline ligandsen_US
dc.titleSynthesis and stimuli-responsive properties of the phenanthroline based metallo-supramolecular polymersen_US
dc.typeArticleen_US

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