2-hydroxyethyl-substituted (NHC)PdI2(pyridine) (Pd-PEPPSI) Complexes: Synthesis, Characterization and the Catalytic Activity in the Sonogashira Cross-coupling Reaction

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dc.authoridAktaş, Aydın/0000-0001-8496-6782;
dc.authorwosidAktaş, Aydın/J-6194-2019
dc.authorwosidGök, Yetkin/AAA-5669-2021
dc.authorwosidBarut Celepci, Duygu/M-6189-2017
dc.contributor.authorErdemir, Fatos
dc.contributor.authorCelepci, Duygu Barut
dc.contributor.authorAktas, Aydin
dc.contributor.authorGok, Yetkin
dc.date.accessioned2024-08-04T20:45:59Z
dc.date.available2024-08-04T20:45:59Z
dc.date.issued2019
dc.departmentİnönü Üniversitesien_US
dc.description.abstractHere, new series of the 2-hydroxyethyl-substituted (NHC)PdI2(pyridine) (Pd-PEPPSI) complexes have been synthesized. These complexes have been prepared from the 2-hydroxyethyl-substituted N-heterocyclic carbene (NHC) precursors, palladium chloride and pyridine. The synthesized Pd-PEPPSI complexes have been characterized by using H-1 NMR, C-13 NMR, FTIR spectroscopy and elemental analysis techniques. The catalytic activity of the 2-hydroxyethyl-substituted Pd-PEPPSI complexes has been examined in the Sonogashira cross-coupling reaction by using phenylacetylene and aryl bromide. The Pd-PEPPSI complexes have demonstrated great activity in the Sonogashira cross-coupling reaction. The molecular and crystal structures of the three of the Pd-PEPPSI complexes were determined by single-crystal X-ray diffraction method. X-ray studies show that all the molecular structures adopt slightly distorted square-planar geometry around the palladium (II) center.en_US
dc.description.sponsorshipDokuz Eylul University [2010.KB.FEN.13]en_US
dc.description.sponsorshipThe authors acknowledge Inonu University Scientific and Technology Center for the elemental analyses of the compounds. The authors acknowledge Dokuz Eylul University for the use of the Oxford Rigaku Xcalibur Eos Diffractometer (purchased under University Research Grant No: 2010.KB.FEN.13).en_US
dc.identifier.doi10.1002/slct.201901033
dc.identifier.endpage5590en_US
dc.identifier.issn2365-6549
dc.identifier.issue19en_US
dc.identifier.scopus2-s2.0-85066254559en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage5585en_US
dc.identifier.urihttps://doi.org/10.1002/slct.201901033
dc.identifier.urihttps://hdl.handle.net/11616/98811
dc.identifier.volume4en_US
dc.identifier.wosWOS:000468976000030en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWiley-V C H Verlag Gmbhen_US
dc.relation.ispartofChemistryselecten_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-Heterocyclic carbenesen_US
dc.subjectPd-PEPPSI complexesen_US
dc.subjectPhenylboronic aciden_US
dc.subjectSuzuki-Miyaura reactionen_US
dc.subjectX-ray diffractionen_US
dc.title2-hydroxyethyl-substituted (NHC)PdI2(pyridine) (Pd-PEPPSI) Complexes: Synthesis, Characterization and the Catalytic Activity in the Sonogashira Cross-coupling Reactionen_US
dc.typeArticleen_US

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