Pentacoordinated Rhodium(I) Complexes Supported by Coumarin-Functionalized N-Heterocyclic Carbene Ligands

Basit Öğe Kaydı
dc.authoridALICI, Bulent/0000-0001-5009-3223
dc.authoridKarataş, Mert Olgun/0000-0001-8500-2088
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridORO, Luis A/0000-0001-7154-7239
dc.authoridPerez-Torrente, Jesus J./0000-0002-3327-0918
dc.authoridCastarlenas Chela, Ricardo/0000-0003-4460-8678
dc.authoridDi Giuseppe, Andrea/0000-0002-3666-5800
dc.authorwosidDi Giuseppe, Andrea/JAN-6510-2023
dc.authorwosidALICI, Bulent/AAG-4203-2019
dc.authorwosidKarataş, Mert Olgun/ABG-7848-2020
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidDi Giuseppe, Andrea/AAE-3866-2021
dc.authorwosidORO, Luis A/GSO-3650-2022
dc.authorwosidPerez-Torrente, Jesus J./F-3569-2011
dc.contributor.authorKaratas, Mert Olgun
dc.contributor.authorDi Giuseppe, Andrea
dc.contributor.authorPassarelli, Vincenzo
dc.contributor.authorAlici, Bulent
dc.contributor.authorPerez-Torrente, Jesus J.
dc.contributor.authorOro, Luis A.
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:44:15Z
dc.date.available2024-08-04T20:44:15Z
dc.date.issued2018
dc.departmentİnönü Üniversitesien_US
dc.description.abstractNew coumarin-tethered benzimidazolium (BzICou(R)HCl) and imidazolium (ICou(R)HCl) salts have been prepared as precursors for coumarin-NHC rhodium(I) complexes RhCl(NHC)(cod). Trigonal bypiramidal pentacoordinated bis-coumarin-NHC rhodium(I) species, RhCl(NHC)(2), can be obtained by heating rhodium-cod derivatives in the presence of coumarin-azolium salts and a base. These unusual species are stabilized by coordination of the unsaturated bond of both coumarin moieties by the same enantioface. The allyl substituent on doubly functionalized NHC competes for coordination with coumarin wingtips. DFT calculations upon coordination of the olefin moieties support the experimental results.en_US
dc.description.sponsorshipSpanish Ministerio de Economia y Competitividad (MINECO/FEDER) [CTQ2013-42532-P, CTQ2016-75884-P]; CSIC under the Project Proyectos Intramurales Especiales [201680I011]; Diputacion General de Aragon [E07]; Spanish Ministerio de Economia y Competitividad (MINECO) [IJCI-2015-27029]en_US
dc.description.sponsorshipFinancial support from the Spanish Ministerio de Economia y Competitividad (MINECO/FEDER) under the Projects CTQ2013-42532-P and CTQ2016-75884-P, the CSIC under the Project Proyectos Intramurales Especiales (201680I011), and the Diputacion General de Aragon (E07) are gratefully acknowledged. M.O.K. thanks Scientific and Technological Research Council of Turkey (TUBITAK). A.D.G. thanks the Spanish Ministerio de Economia y Competitividad (MINECO) for the postdoctoral grant Juan de la Cierva - Incorporacion 2015 (IJCI-2015-27029).en_US
dc.identifier.doi10.1021/acs.organomet.7b00750
dc.identifier.endpage202en_US
dc.identifier.issn0276-7333
dc.identifier.issn1520-6041
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-85040908032en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage191en_US
dc.identifier.urihttps://doi.org/10.1021/acs.organomet.7b00750
dc.identifier.urihttps://hdl.handle.net/11616/98128
dc.identifier.volume37en_US
dc.identifier.wosWOS:000423255600006en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofOrganometallicsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRing-Opening Polymerizationen_US
dc.subjectTransition-Metal-Complexesen_US
dc.subjectC-H Activationen_US
dc.subjectSilver(I) Complexesen_US
dc.subjectRuthenium(Ii) Complexesen_US
dc.subjectBiological-Activityen_US
dc.subjectStereodirecting Ligandsen_US
dc.subjectMolecular-Structureen_US
dc.subjectCatalytic-Activityen_US
dc.subjectCrystal-Structuresen_US
dc.titlePentacoordinated Rhodium(I) Complexes Supported by Coumarin-Functionalized N-Heterocyclic Carbene Ligandsen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu