The modification of aluminium tri-sec-butoxide with different alcohols and chelating ligands: Hydrolysis and condensation of the products

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dc.authorwosidArpac, Ertugrul/C-5471-2016
dc.contributor.authorSayilkan, H
dc.contributor.authorArpac, E
dc.contributor.authorSener, E
dc.date.accessioned2024-08-04T20:11:55Z
dc.date.available2024-08-04T20:11:55Z
dc.date.issued1997
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this work, alcoholysis reactions of aluminium-sec-butoxide, Al(OBu-s)(3), with 2-ethoxyethanol (EtOCH2CH2OH) and 2-butoxyethanol (BuOCH2CH2OH), complexation reactions of Al(OBu-s)(3) and of alcohol-modified Al(OBu-s)(3) with methacrylic acid (MAC) and ethyl acetoacetate (EAAH), and the hydrolysis reactions of Al(OBu-s)(3) and modified Al(OBu-s)(3) are studied in some detail. Alcoholysis reactions of Al(OBu-s)(3) were performed with different mole ratios of 2-ethoxyethanol and 2-butoxyethanol at room temperature and combining ratios were found to be 1:3 [Al(OBu-s)(3):alcohol] by H-1 NMR analyses. Al(OBu-s)(3) and alcohol-modified Al(OBu-s)(3) were reacted at room temperature with equimolar amounts of methacrylic acid and ethyl acetoacetate and the products were characterized by H-1 NMR, GC, FT-IR and elemental analyses. Hydrolysis-condensation reactions of the various compounds thus formed were studied in detail and the products were characterized by gas chromatography, Karl Fisher coulometric titrations, thermal analysis and FT-IR.en_US
dc.identifier.doi10.1080/00945719708003149
dc.identifier.endpage1452en_US
dc.identifier.issn0094-5714
dc.identifier.issue10en_US
dc.identifier.scopus2-s2.0-0031321731en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage1437en_US
dc.identifier.urihttps://doi.org/10.1080/00945719708003149
dc.identifier.urihttps://hdl.handle.net/11616/93089
dc.identifier.volume27en_US
dc.identifier.wosWOS:A1997YK58400002en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherMarcel Dekker Incen_US
dc.relation.ispartofSynthesis and Reactivity in Inorganic and Metal-Organic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSol-Gel Processen_US
dc.subjectAlkoxide Precursorsen_US
dc.subjectChemistryen_US
dc.subjectTitaniumen_US
dc.subjectBoehmiteen_US
dc.subjectGibbsiteen_US
dc.titleThe modification of aluminium tri-sec-butoxide with different alcohols and chelating ligands: Hydrolysis and condensation of the productsen_US
dc.typeArticleen_US

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