INTERMOLECULAR HYDROAMINATION OF STYRENE CATALYZED BY PALLADIUM(II) N-HETEROCYCLIC CARBENE COMPLEXES IN IONIC LIQUID
Küçük Resim Yok
Tarih
2016
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Pergamon-Elsevier Science Ltd
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
PdCl2(NHC)(2) complexes have been synthesized by the reaction of palladium acetate with a series of benzimidazolium and imidazolinium salts and characterized by elemental analysis, H-1 NMR and C-13 NMR spectroscopy. These complexes were used as catalysts for the intermolecular hydroamination reactions between styrene with various anilines in ionic liquid at 160 degrees C and corresponding anti-Markovnikov products were obtained with a selectivity of 100% in good yields.
Açıklama
Anahtar Kelimeler
Intramolecular Hydroamination, Asymmetric Hydroamination, Unactivated Alkenes, Ligands Synthesis, Direct Addition, Silver(I), Amination, Aniline, Olefins, Alkynes
Kaynak
Heterocycles
WoS Q Değeri
Q4
Scopus Q Değeri
Q4
Cilt
92
Sayı
11
