Synthesis and Catalytic Activity of Novel Benzimidazolinylidene-Ruthenium(II) Complexes

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dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridDüşünceli, Serpil Demir/0000-0001-8765-4039
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authorwosidSahin, Onur/KGM-3910-2024
dc.authorwosidDemir, Serpil/AAI-1740-2019
dc.authorwosidDüşünceli, Serpil Demir/AAA-7160-2021
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorDemir, Serpil
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorSahin, Onur
dc.contributor.authorCetinkaya, Bekir
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2024-08-04T20:32:16Z
dc.date.available2024-08-04T20:32:16Z
dc.date.issued2010
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe reaction of [RuCl2(p-cymene)](2) with 1,3-dialkyl-benzimidazolium salts 1a-d in the presence of a small excess of cesium carbonate yields chelated eta(6)-arene, eta(1)-carbene ruthenium complexes 2a-d. All compounds were characterized by elemental analysis, NMR spectroscopy and the molecular structures of two of the complexes were determined by X-ray crystallography. The catalytic activity of RuCl2(eta(6)-arene, eta(1)-benzimidazolinylidene) complexes was evaluated in the direct arylation of 2-phenylpyridine with bromobenzene derivatives.en_US
dc.description.sponsorshipTUBITAK-CNRS (France) [TBAG-U/181 (106T716)]; Inonu University Research Fund [2009/13]; Faculty of Arts and Sciences, Ondokuz Mayiotas University, Turkey [F279]en_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey TUBITAK-CNRS (France) [TBAG-U/181 (106T716)], the Inonu University Research Fund (I.U. B. A. P: 2009/13) and the Faculty of Arts and Sciences, Ondokuz May iota s University, Turkey, for the use of the Stoe IPDS-II diffractometer (purchased from grant no. F279 of the University Research Fund).en_US
dc.identifier.doi10.1055/s-0029-1219187
dc.identifier.endpage500en_US
dc.identifier.issn0936-5214
dc.identifier.issn1437-2096
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-76349116502en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage496en_US
dc.identifier.urihttps://doi.org/10.1055/s-0029-1219187
dc.identifier.urihttps://hdl.handle.net/11616/94973
dc.identifier.wosWOS:000274233900033en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherGeorg Thieme Verlag Kgen_US
dc.relation.ispartofSynletten_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectrutheniumen_US
dc.subjectbenzimidazolinylidene complexesen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectC-H bond activationen_US
dc.subjectarylationen_US
dc.titleSynthesis and Catalytic Activity of Novel Benzimidazolinylidene-Ruthenium(II) Complexesen_US
dc.typeArticleen_US

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