Palladium-carbene catalyzed direct arylation of five-membered heteroaromatics

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dc.authoridYILDIRIM GÜMÜŞHAN, İlkay/0000-0002-7423-5043
dc.authoridKaloğlu, Murat/0000-0002-2770-5532
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridÖzdemir, Namık/0000-0003-3371-9874
dc.authorwosidYILDIRIM GÜMÜŞHAN, İlkay/JVN-8709-2024
dc.authorwosidKaloğlu, Murat/AAA-3956-2021
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidÖzdemir, Namık/J-6434-2015
dc.contributor.authorKaloglu, Murat
dc.contributor.authorKaloglu, Nazan
dc.contributor.authorYlidirim, Ilkay
dc.contributor.authorOzdemir, Namik
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:47:03Z
dc.date.available2024-08-04T20:47:03Z
dc.date.issued2020
dc.departmentİnönü Üniversitesien_US
dc.description.abstractDue to the industrial importance of bi(hetero)arenes, the synthesis of these compounds by homogeneous Pd-catalyzed direct arylation is an important research topic in modern organic chemistry. In this study, PEPPSI-type, (PEPPSI = Pyridine Enhanced Precatalyst Preparation Stabilization and Initiation), new Pd-catalysts with N-heterocyclic carbene ligand were synthesized, and they were used as catalysts in the synthesis of bi(hetero)arenes by direct arylation process. The structures of Pd-carbene complexes were elucidated by different spectroscopic and analytical techniques such as NMR, FT-IR and elemental analysis. The more detailed structural characterization of one of the complexes was determined by single-crystal X-ray diffraction study. Pd-carbene complexes were used as effective catalysts in the direct arylation of five-membered heteroaromatics such as thiophene, furan and thiazole derivatives with (hetero)aryl bromides for 1 h, in the presence of 1 mol% of catalyst loading, and successful results were obtained. (C) 2020 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipOndokuz Mayis University [PYO.FEN.1906.19.001]; Technological and Scientific Research Council of Turkey TUBITAK [117R010]en_US
dc.description.sponsorshipThis study was supported by the Ondokuz Mayis University (Project No: PYO.FEN.1906.19.001) and the Technological and Scientific Research Council of Turkey TUBITAK (Project No: 117R010).en_US
dc.identifier.doi10.1016/j.molstruc.2019.127668
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85077375945en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2019.127668
dc.identifier.urihttps://hdl.handle.net/11616/99128
dc.identifier.volume1206en_US
dc.identifier.wosWOS:000517780500048en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-Heterocyclic carbeneen_US
dc.subjectPalladiumen_US
dc.subjectPEPPSIen_US
dc.subjectDirect arylationen_US
dc.subjectHeteroaromaticsen_US
dc.titlePalladium-carbene catalyzed direct arylation of five-membered heteroaromaticsen_US
dc.typeArticleen_US

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