Syntheses and catalytic properties of alternating copolymers of poly[4-maleimidopyridyl(p-cymene)dichloro Ru(II)] with ?-methacryloxypropyl trimethoxysilane

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authoridKoytepe, Suleyman/0000-0002-4788-278X
dc.authorwosidKöytepe, Süleyman/AAA-4168-2021
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorÖzdemir, I
dc.contributor.authorÇetinkaya, B
dc.contributor.authorSeçkin, T
dc.contributor.authorKöytepe, S
dc.date.accessioned2024-08-04T20:13:12Z
dc.date.available2024-08-04T20:13:12Z
dc.date.issued2002
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA new monomer, 4-maleimidopyridyl(p-cymene)dichloro Ru(II), was synthesized by the reaction of maleic anhyride with p-dimethylaminopyridine(p-cymene)dichloro ruthenium(II). The homopolymer ofmaleimidopyridyl(p-cymene)dichloro Ru(II) and its copolymers with gamma-methacryloxypropyl trimethoxysilane were prepared by radical polymerization with benzoyl peroxide as an initiator at 75 degreesC. The structures of the synthesized monomer and polymers were identified by Fourier transform infrared, H-1 NMR, and C-13 NMR spectroscopies. Thermal behavior of the polymers were determined by differential thermal analysis, and thermogravimetric analysis, glass transition temperature was determined by differential scanning calorimeter. Excellent selectivities were observed by using Ru (II) complex as the catalyst in hydrosilylation reactions. The heterogeneous Ru(II) catalyst can also be recyled and reused without significant loss of selectivity or activity. (C) 2002 Elsevier Science B.V. All rights reserved.en_US
dc.identifier.doi10.1016/S1381-1169(01)00392-2
dc.identifier.endpage270en_US
dc.identifier.issn1381-1169
dc.identifier.issue1-2en_US
dc.identifier.scopus2-s2.0-0037127471en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage263en_US
dc.identifier.urihttps://doi.org/10.1016/S1381-1169(01)00392-2
dc.identifier.urihttps://hdl.handle.net/11616/93467
dc.identifier.volume179en_US
dc.identifier.wosWOS:000173811100030en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Bven_US
dc.relation.ispartofJournal of Molecular Catalysis A-Chemicalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRu(II) catalysten_US
dc.subjectmetal complex catalysten_US
dc.subjectpoly(4-maleimidopyridine)en_US
dc.subjectpolyimideen_US
dc.subjecthydrosilylationen_US
dc.titleSyntheses and catalytic properties of alternating copolymers of poly[4-maleimidopyridyl(p-cymene)dichloro Ru(II)] with ?-methacryloxypropyl trimethoxysilaneen_US
dc.typeArticleen_US

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