Mixed phosphine/N-heterocyclic carbene-palladium complexes: synthesis, characterization, crystal structure and application in the Sonogashira reaction in aqueous media

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dc.authoridAktaş, Aydın/0000-0001-8496-6782
dc.authoridAygün, Muhittin/0000-0001-9670-9062
dc.authorwosidGök, Yetkin/AAA-5669-2021
dc.authorwosidBarut Celepci, Duygu/M-6189-2017
dc.authorwosidAktaş, Aydın/J-6194-2019
dc.authorwosidAygün, Muhittin/P-3605-2019
dc.contributor.authorAktas, Aydin
dc.contributor.authorErdemir, Fatos
dc.contributor.authorCelepci, Duygu Barut
dc.contributor.authorGok, Yetkin
dc.contributor.authorAygun, Muhittin
dc.date.accessioned2024-08-04T20:45:32Z
dc.date.available2024-08-04T20:45:32Z
dc.date.issued2019
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA series of 2-hydroxyethyl-substituted N-heterocyclic carbene-(NHC)PdX2PPh3 complexes have been synthesized by substitution of the pyridine or 3-chloropyridine ligand in (NHC)PdX2(pyridine/3-chloropyridine) complexes with triphenylphosphine. The new complexes were characterized by H-1, C-13 {H-1}, P-31 {H-1}NMR, FTIR spectroscopy and elemental analysis. Also, the molecular and crystal structures of 1c and 1d have been obtained by single-crystal X-ray diffraction. The 2-hydroxyethyl-substituted (NHC)PdX2PPh3 complexes have been examined as catalysts for the Sonogashira cross-coupling reaction in water/DMF solvent mixtures.en_US
dc.description.sponsorshipDokuz Eylul University [2010.KB.FEN.13]en_US
dc.description.sponsorshipThe authors acknowledge Dokuz Eylul University for the use of the Oxford Rigaku Xcalibur Eos Diffractometer (purchased under University Research Grant No: 2010.KB.FEN.13). The authors thank the nonu University Faculty of Science Department of Chemistry for the spectroscopy data and nonu University Scientific and Technology Center for the elemental analyses of the compounds.en_US
dc.identifier.doi10.1007/s11243-018-0286-5
dc.identifier.endpage236en_US
dc.identifier.issn0340-4285
dc.identifier.issn1572-901X
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-85056251393en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage229en_US
dc.identifier.urihttps://doi.org/10.1007/s11243-018-0286-5
dc.identifier.urihttps://hdl.handle.net/11616/98531
dc.identifier.volume44en_US
dc.identifier.wosWOS:000463677600003en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofTransition Metal Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCoupling Reactionen_US
dc.subjectSuzuki-Miyauraen_US
dc.subjectAryl Chloridesen_US
dc.subjectCopper Freeen_US
dc.subjectLigandsen_US
dc.subjectCatalystsen_US
dc.subjectEfficienten_US
dc.titleMixed phosphine/N-heterocyclic carbene-palladium complexes: synthesis, characterization, crystal structure and application in the Sonogashira reaction in aqueous mediaen_US
dc.typeArticleen_US

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