Synthesis of bridged palladium-PEPPSI complexes and catalytic studies in C-C cross-coupling reactions

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridYaşar, Sedat/0000-0001-7285-2761
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidYaşar, Sedat/ABG-8356-2020
dc.contributor.authorImik, Fatma
dc.contributor.authorYasar, Sedat
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:46:01Z
dc.date.available2024-08-04T20:46:01Z
dc.date.issued2019
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA series of dimetallic NHC-Pd-PEPPSI complexes with phenylene-bridged N-heterocyclic carbenes (NHC) were synthesized and fully characterized by H-1 NMR, C-13 NMR, HRMS, FTIR, and elemental analysis. The N tags were 2,3,4,5,6-pentamethylbenzyl, 3,5-dimethylbenzyl, 4-tert-butylbenzyl and 3-methoxybenzyl groups. The catalytic properties of the complexes were investigated in the Suzuki-Miyaura reactions of aryl bromides with arylboronic acid and in the Heck coupling reactions of aryl bromide with styrene and in the Sonogashira reactions of aryl bromides with phenylacetylene. Generally, dimetallic complexes exhibit good catalytic activities in the Suzuki-Miyaura, Heck, and Sonogashira coupling reactions.en_US
dc.identifier.doi10.1016/j.ica.2019.118969
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopus2-s2.0-85067609981en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2019.118969
dc.identifier.urihttps://hdl.handle.net/11616/98838
dc.identifier.volume495en_US
dc.identifier.wosWOS:000481728800038en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPalladium N-heterocyclic carbene complexen_US
dc.subjectSuzuki couplingen_US
dc.subjectSonogashira couplingen_US
dc.subjectHeck couplingen_US
dc.titleSynthesis of bridged palladium-PEPPSI complexes and catalytic studies in C-C cross-coupling reactionsen_US
dc.typeArticleen_US

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