Enhanced catalytic performance of silica-supported Pd-NHC complexes in Suzuki-Miyaura coupling reactions

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dc.contributor.authorAkkoc, Mitat
dc.contributor.authorKoc, Hatice Kubra
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2026-04-04T13:34:54Z
dc.date.available2026-04-04T13:34:54Z
dc.date.issued2025
dc.departmentİnönü Üniversitesi
dc.description.abstractSince silica-supported catalysts are effective due to their rigid but porous structure, which lacks thermal and chemical stability and swelling properties, the characteristic structure of this heterogeneous catalyst we synthesized was elucidated using methods such as NMR, XRD, FTIR, SEM, DTA, and TGA. In this study, benzimidazolium salt was first synthesized and then converted into a Pd-NHC complex. The synthesized Pd-NHC complex was bonded to the SiO2 structure, and heterogeneous SiO2@NHC@Pd was synthesized. The Suzuki-Miyaura C-C coupling reaction of this SiO2@NHC@Pd catalyst was successfully carried out under mild conditions in the presence of green solvents.
dc.identifier.doi10.1016/j.molstruc.2024.141006
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.orcid0000-0001-6325-0216
dc.identifier.orcid0000-0001-8641-8958
dc.identifier.scopus2-s2.0-85211752917
dc.identifier.scopusqualityQ1
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2024.141006
dc.identifier.urihttps://hdl.handle.net/11616/109487
dc.identifier.volume1325
dc.identifier.wosWOS:001389382100001
dc.identifier.wosqualityQ2
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoen
dc.publisherElsevier
dc.relation.ispartofJournal of Molecular Structure
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/closedAccess
dc.snmzKA_WOS_20250329
dc.subjectNHC
dc.subjectSilica
dc.subjectPalladium
dc.subjectHeterogen
dc.titleEnhanced catalytic performance of silica-supported Pd-NHC complexes in Suzuki-Miyaura coupling reactions
dc.typeArticle

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